TY - JOUR
T1 - Photocatalytic nanofiber membranes for the degradation of micropollutants and their antimicrobial activity
T2 - Recent advances and future prospects
AU - Chabalala, Mandla B.
AU - Gumbi, Nozipho N.
AU - Mamba, Bhekie B.
AU - Al-Abri, Mohammed Z.
AU - Nxumalo, Edward N.
N1 - Funding Information:
The authors would like to gratefully acknowledge The University of South Africa, in particular the Institute of Nanotechnology and Water Sustainability for allowing access to their facilities and for financially supporting this work.
Publisher Copyright:
© 2021 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2021/9
Y1 - 2021/9
N2 - This review paper systematically evaluates current progress on the development and performance of photocatalytic nanofiber membranes often used in the removal of micropollutants from water systems. It is demonstrated that nanofiber membranes serve as excellent support materials for photocatalytic nanoparticles, leading to nanofiber membranes with enhanced optical properties, as well as improved recovery, recyclability, and reusability. The tremendous performance of pho-tocatalytic membranes is attributed to the photogenerated reactive oxygen species such as hydroxyl radicals, singlet oxygen, and superoxide anion radicals introduced by catalytic nanoparticles such as TiO2 and ZnO upon light irradiation. Hydroxyl radicals are the most reactive species responsible for most of the photodegradation processes of these unwanted pollutants. The review also demonstrates that self-cleaning and antimicrobial nanofiber membranes are useful in the removal of microbial species in water. These unique materials are also applicable in other fields such as wound dressing since the membrane allows for oxygen flow in wounds to heal while antimicrobial agents protect wounds against infections. It is demonstrated that antimicrobial activities against bacteria and photocatalytic degradation of micropollutants significantly reduce membrane fouling. There-fore, the review demonstrates that electrospun photocatalytic nanofiber membranes with antimi-crobial activity form efficient cost-effective multifunctional composite materials for the removal of unwanted species in water and for use in various other applications such as filtration, adsorption and electrocatalysis.
AB - This review paper systematically evaluates current progress on the development and performance of photocatalytic nanofiber membranes often used in the removal of micropollutants from water systems. It is demonstrated that nanofiber membranes serve as excellent support materials for photocatalytic nanoparticles, leading to nanofiber membranes with enhanced optical properties, as well as improved recovery, recyclability, and reusability. The tremendous performance of pho-tocatalytic membranes is attributed to the photogenerated reactive oxygen species such as hydroxyl radicals, singlet oxygen, and superoxide anion radicals introduced by catalytic nanoparticles such as TiO2 and ZnO upon light irradiation. Hydroxyl radicals are the most reactive species responsible for most of the photodegradation processes of these unwanted pollutants. The review also demonstrates that self-cleaning and antimicrobial nanofiber membranes are useful in the removal of microbial species in water. These unique materials are also applicable in other fields such as wound dressing since the membrane allows for oxygen flow in wounds to heal while antimicrobial agents protect wounds against infections. It is demonstrated that antimicrobial activities against bacteria and photocatalytic degradation of micropollutants significantly reduce membrane fouling. There-fore, the review demonstrates that electrospun photocatalytic nanofiber membranes with antimi-crobial activity form efficient cost-effective multifunctional composite materials for the removal of unwanted species in water and for use in various other applications such as filtration, adsorption and electrocatalysis.
KW - Antimicrobial properties
KW - Micropollutants
KW - Nanofiber membranes
KW - Photocatalysis
KW - Wastewater treatment
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U2 - 10.3390/membranes11090678
DO - 10.3390/membranes11090678
M3 - Review article
C2 - 34564496
AN - SCOPUS:85114506409
SN - 2077-0375
VL - 11
JO - Membranes
JF - Membranes
IS - 9
M1 - 678
ER -