Phosphonium-based ionic liquids analogues and their physical properties

Mukhtar A. Kareem, Farouq S. Mjalli, Mohd Ali Hashim, Inas M. Alnashef

Research output: Contribution to journalArticle

166 Citations (Scopus)

Abstract

New ionic liquids analogues, that is, deep eutectic solvents (DESs), have been successfully synthesized. These DESs have been synthesized by the reaction of phosphonium-based salts with different hydrogen bond donors. Many of these DESs have melting temperatures lower than 100 °C. Preliminary laboratory results showed that these DESs can be used in different applications, for example, electrochemical processes, separation of sugars, and so forth. Melting temperature, density, viscosity, pH, conductivity, and dissolved oxygen content of the novel phosphonium-based DESs were measured as a function of temperature. It was found that the type of the salt and hydrogen bond donor and the mole ratio of both compounds have a paramount effect on the studied properties.

Original languageEnglish
Pages (from-to)4632-4637
Number of pages6
JournalJournal of Chemical and Engineering Data
Volume55
Issue number11
DOIs
Publication statusPublished - Nov 11 2010

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Ionic Liquids
Ionic liquids
Eutectics
Physical properties
Melting point
Hydrogen bonds
Salts
Dissolved oxygen
Sugars
Viscosity

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Phosphonium-based ionic liquids analogues and their physical properties. / Kareem, Mukhtar A.; Mjalli, Farouq S.; Hashim, Mohd Ali; Alnashef, Inas M.

In: Journal of Chemical and Engineering Data, Vol. 55, No. 11, 11.11.2010, p. 4632-4637.

Research output: Contribution to journalArticle

Kareem, Mukhtar A. ; Mjalli, Farouq S. ; Hashim, Mohd Ali ; Alnashef, Inas M. / Phosphonium-based ionic liquids analogues and their physical properties. In: Journal of Chemical and Engineering Data. 2010 ; Vol. 55, No. 11. pp. 4632-4637.
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