Petrogenesis of early cretaceous carbonatite and ultramafic lamprophyres in a diatreme in the Batain Nappes, Eastern Oman continental margin

S. Nasir, S. Al-Khirbash, H. Rollinson, A. Al-Harthy, A. Al-Sayigh, A. Al-Lazki, T. Theye, H. J. Massonne, E. Belousova

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Allochthonous carbonatite and ultramafic lamprophyre occur in a diatreme at the beach of the Asseelah village, northeastern Oman. The diatreme consists of heterogeneous deposits dominated by 'diatreme facies' pyroclastic rocks. These include aillikite and carbonatite, which intrude late Jurassic to early Cretaceous cherts and shales of the Wahra Formation within the Batain nappes. Both rock types are dominated by carbonate, altered olivine, Ti-Al-phlogopite and Cr-Al-spinel and contain varying amounts of apatite and rutile. The carbonatite occur as fine-grained heterolithic breccias with abundant rounded carbonatite xenoliths, glimmerite and crustal xenoliths. The aillikite consists of pelletal lapilli tuff with abundant fine-grained carbonatite autoliths and crustal xenoliths, which resemble those in the carbonatite breccia. The aillikite and carbonatite are characterized by low SiO2 (11-24 wt%), MgO (9.5-12.4 wt%) and K2O (2O3 (4.75-7.04 wt%), Fe2O3tot (8.7-13.8 wt%) and loss-on-ignition (24-30 wt%). Higher CaO, Fe2O3total, Al2O3, MnO, TiO2, P2O5 and lower SiO2 and MgO content distinguish carbonatite from the aillikite. The associated carbonatite xenoliths and autoliths have intermediate composition between the aillikite and carbonatite. Mg number is variable and ranges between 58 and 66 in the carbonatite, 66 and 72 in the aillikite and between 48 to 64 in the carbonatite autoliths and xenoliths. The Asseelah aillikite, carbonatite, carbonatite xenoliths and autoliths overlap in most of their mineral parageneses, mineral composition and major and trace element chemistry and have variable but overlapping Sr, Nd and Pb isotopic composition, implying that these rocks are related to a common type of parental magma with variable isotopic characteristics. The Asseelah aillikite, carbonatite and carbonatites xenoliths are LREE-enriched and significantly depleted in HREE. They exhibit similar smooth, subparallel REE pattern and steep slopes with (La/Sm)n of 6-10 and relative depletion in heavy rare earth elements (Lu = 3-10 chondrite). Initial 87Sr/86Sr ratios vary from 0.70409 to 0.70787, whereas initial 143Nd/144Nd ratios vary between 0.512603 and 0.512716 (εNdi between 2.8 and 3.6). 206Pb/204Pbi ratios vary between 18.4 and 18.76, 207Pb/204Pbi ratios vary between 15.34 and 15.63, whereas 208Pb/204Pbi varies between 38.42 and 39.05. Zircons grains extracted from the carbonatite have a mean age of 137 ± 1 Ma (95% confidence, MSWD = 0.49). This age correlates with large-scale tectonic events recorded in the early Indian Ocean at 140-160 Ma. Geochemical and isotopic signatures displayed by the Asseelah rocks can be accounted for by vein-plus-wall-rock model of Foley (1992) wherein veins are represented by phlogopite, carbonate and apatite and depleted peridotite constitutes the wall-rock. The carbonatite and aillikite magmatism is probably a distal effect of the breaking up of Gondwana, during and/or after the rift-to-drift transition that led to the opening of the Indian Ocean.

Original languageEnglish
Pages (from-to)47-74
Number of pages28
JournalContributions to Mineralogy and Petrology
Volume161
Issue number1
DOIs
Publication statusPublished - 2011

Fingerprint

Oman
diatreme
folds (geology)
petrogenesis
carbonatite
continental shelves
nappe
continental margin
Rocks
Wall rock
rocks
Cretaceous
phosphorus pentoxide
Minerals
Indian Ocean
Chemical analysis
apatites
veins
Apatites
Carbonates

Keywords

  • Aillikite
  • Batain Nappes
  • Carbonatite
  • Gondwana
  • Oman
  • Ultramafic lamprophyre

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geophysics

Cite this

Petrogenesis of early cretaceous carbonatite and ultramafic lamprophyres in a diatreme in the Batain Nappes, Eastern Oman continental margin. / Nasir, S.; Al-Khirbash, S.; Rollinson, H.; Al-Harthy, A.; Al-Sayigh, A.; Al-Lazki, A.; Theye, T.; Massonne, H. J.; Belousova, E.

In: Contributions to Mineralogy and Petrology, Vol. 161, No. 1, 2011, p. 47-74.

Research output: Contribution to journalArticle

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abstract = "Allochthonous carbonatite and ultramafic lamprophyre occur in a diatreme at the beach of the Asseelah village, northeastern Oman. The diatreme consists of heterogeneous deposits dominated by 'diatreme facies' pyroclastic rocks. These include aillikite and carbonatite, which intrude late Jurassic to early Cretaceous cherts and shales of the Wahra Formation within the Batain nappes. Both rock types are dominated by carbonate, altered olivine, Ti-Al-phlogopite and Cr-Al-spinel and contain varying amounts of apatite and rutile. The carbonatite occur as fine-grained heterolithic breccias with abundant rounded carbonatite xenoliths, glimmerite and crustal xenoliths. The aillikite consists of pelletal lapilli tuff with abundant fine-grained carbonatite autoliths and crustal xenoliths, which resemble those in the carbonatite breccia. The aillikite and carbonatite are characterized by low SiO2 (11-24 wt{\%}), MgO (9.5-12.4 wt{\%}) and K2O (2O3 (4.75-7.04 wt{\%}), Fe2O3tot (8.7-13.8 wt{\%}) and loss-on-ignition (24-30 wt{\%}). Higher CaO, Fe2O3total, Al2O3, MnO, TiO2, P2O5 and lower SiO2 and MgO content distinguish carbonatite from the aillikite. The associated carbonatite xenoliths and autoliths have intermediate composition between the aillikite and carbonatite. Mg number is variable and ranges between 58 and 66 in the carbonatite, 66 and 72 in the aillikite and between 48 to 64 in the carbonatite autoliths and xenoliths. The Asseelah aillikite, carbonatite, carbonatite xenoliths and autoliths overlap in most of their mineral parageneses, mineral composition and major and trace element chemistry and have variable but overlapping Sr, Nd and Pb isotopic composition, implying that these rocks are related to a common type of parental magma with variable isotopic characteristics. The Asseelah aillikite, carbonatite and carbonatites xenoliths are LREE-enriched and significantly depleted in HREE. They exhibit similar smooth, subparallel REE pattern and steep slopes with (La/Sm)n of 6-10 and relative depletion in heavy rare earth elements (Lu = 3-10 chondrite). Initial 87Sr/86Sr ratios vary from 0.70409 to 0.70787, whereas initial 143Nd/144Nd ratios vary between 0.512603 and 0.512716 (εNdi between 2.8 and 3.6). 206Pb/204Pbi ratios vary between 18.4 and 18.76, 207Pb/204Pbi ratios vary between 15.34 and 15.63, whereas 208Pb/204Pbi varies between 38.42 and 39.05. Zircons grains extracted from the carbonatite have a mean age of 137 ± 1 Ma (95{\%} confidence, MSWD = 0.49). This age correlates with large-scale tectonic events recorded in the early Indian Ocean at 140-160 Ma. Geochemical and isotopic signatures displayed by the Asseelah rocks can be accounted for by vein-plus-wall-rock model of Foley (1992) wherein veins are represented by phlogopite, carbonate and apatite and depleted peridotite constitutes the wall-rock. The carbonatite and aillikite magmatism is probably a distal effect of the breaking up of Gondwana, during and/or after the rift-to-drift transition that led to the opening of the Indian Ocean.",
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T1 - Petrogenesis of early cretaceous carbonatite and ultramafic lamprophyres in a diatreme in the Batain Nappes, Eastern Oman continental margin

AU - Nasir, S.

AU - Al-Khirbash, S.

AU - Rollinson, H.

AU - Al-Harthy, A.

AU - Al-Sayigh, A.

AU - Al-Lazki, A.

AU - Theye, T.

AU - Massonne, H. J.

AU - Belousova, E.

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N2 - Allochthonous carbonatite and ultramafic lamprophyre occur in a diatreme at the beach of the Asseelah village, northeastern Oman. The diatreme consists of heterogeneous deposits dominated by 'diatreme facies' pyroclastic rocks. These include aillikite and carbonatite, which intrude late Jurassic to early Cretaceous cherts and shales of the Wahra Formation within the Batain nappes. Both rock types are dominated by carbonate, altered olivine, Ti-Al-phlogopite and Cr-Al-spinel and contain varying amounts of apatite and rutile. The carbonatite occur as fine-grained heterolithic breccias with abundant rounded carbonatite xenoliths, glimmerite and crustal xenoliths. The aillikite consists of pelletal lapilli tuff with abundant fine-grained carbonatite autoliths and crustal xenoliths, which resemble those in the carbonatite breccia. The aillikite and carbonatite are characterized by low SiO2 (11-24 wt%), MgO (9.5-12.4 wt%) and K2O (2O3 (4.75-7.04 wt%), Fe2O3tot (8.7-13.8 wt%) and loss-on-ignition (24-30 wt%). Higher CaO, Fe2O3total, Al2O3, MnO, TiO2, P2O5 and lower SiO2 and MgO content distinguish carbonatite from the aillikite. The associated carbonatite xenoliths and autoliths have intermediate composition between the aillikite and carbonatite. Mg number is variable and ranges between 58 and 66 in the carbonatite, 66 and 72 in the aillikite and between 48 to 64 in the carbonatite autoliths and xenoliths. The Asseelah aillikite, carbonatite, carbonatite xenoliths and autoliths overlap in most of their mineral parageneses, mineral composition and major and trace element chemistry and have variable but overlapping Sr, Nd and Pb isotopic composition, implying that these rocks are related to a common type of parental magma with variable isotopic characteristics. The Asseelah aillikite, carbonatite and carbonatites xenoliths are LREE-enriched and significantly depleted in HREE. They exhibit similar smooth, subparallel REE pattern and steep slopes with (La/Sm)n of 6-10 and relative depletion in heavy rare earth elements (Lu = 3-10 chondrite). Initial 87Sr/86Sr ratios vary from 0.70409 to 0.70787, whereas initial 143Nd/144Nd ratios vary between 0.512603 and 0.512716 (εNdi between 2.8 and 3.6). 206Pb/204Pbi ratios vary between 18.4 and 18.76, 207Pb/204Pbi ratios vary between 15.34 and 15.63, whereas 208Pb/204Pbi varies between 38.42 and 39.05. Zircons grains extracted from the carbonatite have a mean age of 137 ± 1 Ma (95% confidence, MSWD = 0.49). This age correlates with large-scale tectonic events recorded in the early Indian Ocean at 140-160 Ma. Geochemical and isotopic signatures displayed by the Asseelah rocks can be accounted for by vein-plus-wall-rock model of Foley (1992) wherein veins are represented by phlogopite, carbonate and apatite and depleted peridotite constitutes the wall-rock. The carbonatite and aillikite magmatism is probably a distal effect of the breaking up of Gondwana, during and/or after the rift-to-drift transition that led to the opening of the Indian Ocean.

AB - Allochthonous carbonatite and ultramafic lamprophyre occur in a diatreme at the beach of the Asseelah village, northeastern Oman. The diatreme consists of heterogeneous deposits dominated by 'diatreme facies' pyroclastic rocks. These include aillikite and carbonatite, which intrude late Jurassic to early Cretaceous cherts and shales of the Wahra Formation within the Batain nappes. Both rock types are dominated by carbonate, altered olivine, Ti-Al-phlogopite and Cr-Al-spinel and contain varying amounts of apatite and rutile. The carbonatite occur as fine-grained heterolithic breccias with abundant rounded carbonatite xenoliths, glimmerite and crustal xenoliths. The aillikite consists of pelletal lapilli tuff with abundant fine-grained carbonatite autoliths and crustal xenoliths, which resemble those in the carbonatite breccia. The aillikite and carbonatite are characterized by low SiO2 (11-24 wt%), MgO (9.5-12.4 wt%) and K2O (2O3 (4.75-7.04 wt%), Fe2O3tot (8.7-13.8 wt%) and loss-on-ignition (24-30 wt%). Higher CaO, Fe2O3total, Al2O3, MnO, TiO2, P2O5 and lower SiO2 and MgO content distinguish carbonatite from the aillikite. The associated carbonatite xenoliths and autoliths have intermediate composition between the aillikite and carbonatite. Mg number is variable and ranges between 58 and 66 in the carbonatite, 66 and 72 in the aillikite and between 48 to 64 in the carbonatite autoliths and xenoliths. The Asseelah aillikite, carbonatite, carbonatite xenoliths and autoliths overlap in most of their mineral parageneses, mineral composition and major and trace element chemistry and have variable but overlapping Sr, Nd and Pb isotopic composition, implying that these rocks are related to a common type of parental magma with variable isotopic characteristics. The Asseelah aillikite, carbonatite and carbonatites xenoliths are LREE-enriched and significantly depleted in HREE. They exhibit similar smooth, subparallel REE pattern and steep slopes with (La/Sm)n of 6-10 and relative depletion in heavy rare earth elements (Lu = 3-10 chondrite). Initial 87Sr/86Sr ratios vary from 0.70409 to 0.70787, whereas initial 143Nd/144Nd ratios vary between 0.512603 and 0.512716 (εNdi between 2.8 and 3.6). 206Pb/204Pbi ratios vary between 18.4 and 18.76, 207Pb/204Pbi ratios vary between 15.34 and 15.63, whereas 208Pb/204Pbi varies between 38.42 and 39.05. Zircons grains extracted from the carbonatite have a mean age of 137 ± 1 Ma (95% confidence, MSWD = 0.49). This age correlates with large-scale tectonic events recorded in the early Indian Ocean at 140-160 Ma. Geochemical and isotopic signatures displayed by the Asseelah rocks can be accounted for by vein-plus-wall-rock model of Foley (1992) wherein veins are represented by phlogopite, carbonate and apatite and depleted peridotite constitutes the wall-rock. The carbonatite and aillikite magmatism is probably a distal effect of the breaking up of Gondwana, during and/or after the rift-to-drift transition that led to the opening of the Indian Ocean.

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