Novel alkyl ether sulfonates for high salinity reservoir

Effect of concentration on transient ultralow interfacial tension at the oil-water interface

Mohamed Aoudia, Zuleihka Al-Harthi, Rashid S. Al-Maamari, Christie Lee, Paul Berger

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The effect of surfactant concentration on the occurrence and detection of transient ultralow interfacial tension (IFT) between crude oil and formation water at 75 °C has been investigated using a series of novel sodium alkyl ether sulfonates having various increasing molecular weights and degrees of ethoxylation. All surfactant systems displayed dynamic interfacial tension (DIT). Transient ultralow DIT (DITmin) were detected only within an intermediate surfactant concentration. This behavior was attributed to an implicit concentration-related length scale required for the added surfactant to diffuse from the bulk phase to the freshly prepared oil-water interface. In the high surfactant concentration range, this length scale is relatively short and results in an instantaneous (and undetectable) occurrence of DITmim in a relatively very short time scale, well beyond the detection limit of the spinning drop tensiometer (∼2-3 min). Interestingly, DITmin were detected only in systems above the surfactant's critical micelle concentration, suggesting that DITmin occurs as a result of the diffusion (subsequent to the adsorption) of the oil acidic species from the interface to the bulk phase to form mixed micelles with the added surfactant. Measurements of DITs in the presence of decane showed no evidence for DITmin, confirming the general belief that DITmin is indeed due to the interaction of the added surfactant with the oil acidic components. Finally, the effect of surfactant concentration on the equilibrium IFT (γ eq) showed evidence for relatively low values (∼ 10-2 mNm-1) for some surfactant systems.

Original languageEnglish
Pages (from-to)233-242
Number of pages10
JournalJournal of Surfactants and Detergents
Volume13
Issue number3
DOIs
Publication statusPublished - Jul 2010

Fingerprint

salinity
sulfonates
Surface-Active Agents
Ether
Surface tension
Ethers
ethers
interfacial tension
Oils
Surface active agents
oils
surfactants
Water
water
micelles
tensiometers
occurrences
Critical micelle concentration
Petroleum
Micelles

Keywords

  • Alkyl ether sulfonates
  • Dynamic interfacial tension
  • Enhanced oil recovery
  • Transient ultralow interfacial tension

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Chemical Engineering(all)
  • Surfaces, Coatings and Films

Cite this

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title = "Novel alkyl ether sulfonates for high salinity reservoir: Effect of concentration on transient ultralow interfacial tension at the oil-water interface",
abstract = "The effect of surfactant concentration on the occurrence and detection of transient ultralow interfacial tension (IFT) between crude oil and formation water at 75 °C has been investigated using a series of novel sodium alkyl ether sulfonates having various increasing molecular weights and degrees of ethoxylation. All surfactant systems displayed dynamic interfacial tension (DIT). Transient ultralow DIT (DITmin) were detected only within an intermediate surfactant concentration. This behavior was attributed to an implicit concentration-related length scale required for the added surfactant to diffuse from the bulk phase to the freshly prepared oil-water interface. In the high surfactant concentration range, this length scale is relatively short and results in an instantaneous (and undetectable) occurrence of DITmim in a relatively very short time scale, well beyond the detection limit of the spinning drop tensiometer (∼2-3 min). Interestingly, DITmin were detected only in systems above the surfactant's critical micelle concentration, suggesting that DITmin occurs as a result of the diffusion (subsequent to the adsorption) of the oil acidic species from the interface to the bulk phase to form mixed micelles with the added surfactant. Measurements of DITs in the presence of decane showed no evidence for DITmin, confirming the general belief that DITmin is indeed due to the interaction of the added surfactant with the oil acidic components. Finally, the effect of surfactant concentration on the equilibrium IFT (γ eq) showed evidence for relatively low values (∼ 10-2 mNm-1) for some surfactant systems.",
keywords = "Alkyl ether sulfonates, Dynamic interfacial tension, Enhanced oil recovery, Transient ultralow interfacial tension",
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T2 - Effect of concentration on transient ultralow interfacial tension at the oil-water interface

AU - Aoudia, Mohamed

AU - Al-Harthi, Zuleihka

AU - Al-Maamari, Rashid S.

AU - Lee, Christie

AU - Berger, Paul

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N2 - The effect of surfactant concentration on the occurrence and detection of transient ultralow interfacial tension (IFT) between crude oil and formation water at 75 °C has been investigated using a series of novel sodium alkyl ether sulfonates having various increasing molecular weights and degrees of ethoxylation. All surfactant systems displayed dynamic interfacial tension (DIT). Transient ultralow DIT (DITmin) were detected only within an intermediate surfactant concentration. This behavior was attributed to an implicit concentration-related length scale required for the added surfactant to diffuse from the bulk phase to the freshly prepared oil-water interface. In the high surfactant concentration range, this length scale is relatively short and results in an instantaneous (and undetectable) occurrence of DITmim in a relatively very short time scale, well beyond the detection limit of the spinning drop tensiometer (∼2-3 min). Interestingly, DITmin were detected only in systems above the surfactant's critical micelle concentration, suggesting that DITmin occurs as a result of the diffusion (subsequent to the adsorption) of the oil acidic species from the interface to the bulk phase to form mixed micelles with the added surfactant. Measurements of DITs in the presence of decane showed no evidence for DITmin, confirming the general belief that DITmin is indeed due to the interaction of the added surfactant with the oil acidic components. Finally, the effect of surfactant concentration on the equilibrium IFT (γ eq) showed evidence for relatively low values (∼ 10-2 mNm-1) for some surfactant systems.

AB - The effect of surfactant concentration on the occurrence and detection of transient ultralow interfacial tension (IFT) between crude oil and formation water at 75 °C has been investigated using a series of novel sodium alkyl ether sulfonates having various increasing molecular weights and degrees of ethoxylation. All surfactant systems displayed dynamic interfacial tension (DIT). Transient ultralow DIT (DITmin) were detected only within an intermediate surfactant concentration. This behavior was attributed to an implicit concentration-related length scale required for the added surfactant to diffuse from the bulk phase to the freshly prepared oil-water interface. In the high surfactant concentration range, this length scale is relatively short and results in an instantaneous (and undetectable) occurrence of DITmim in a relatively very short time scale, well beyond the detection limit of the spinning drop tensiometer (∼2-3 min). Interestingly, DITmin were detected only in systems above the surfactant's critical micelle concentration, suggesting that DITmin occurs as a result of the diffusion (subsequent to the adsorption) of the oil acidic species from the interface to the bulk phase to form mixed micelles with the added surfactant. Measurements of DITs in the presence of decane showed no evidence for DITmin, confirming the general belief that DITmin is indeed due to the interaction of the added surfactant with the oil acidic components. Finally, the effect of surfactant concentration on the equilibrium IFT (γ eq) showed evidence for relatively low values (∼ 10-2 mNm-1) for some surfactant systems.

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