N,N-Dimethyl-5-methoxymethyl-2′-deoxycytidine

Gerald F. Audette, Wajdi M. Zoghaib, Sagar V. Gupta, J. Wilson Quail, Louis T J Delbaere

Research output: Contribution to journalArticle

Abstract

In the title compound, C13H21N3O5, the pyrimidine ring adopts the antiperiplanar (-ap) conformation [ χ = 193.54 (19)°]. The deoxyribose sugar ring has the C2′-exo-C3′-endo (2T3) twist conformation. The pseudo-rotational parameters of the deoxyribose sugar ring are P = 6.83 (2)° and τm = 38.27 (2)°. The exocyclic side chain at C5′ has the g+ conformation [γ = 47.7 (3)°]. The 5-methoxymethyl group is distal to the deoxyribose sugar ring, with a C6-C5-C52-O52 torsion angle of -91.9 (3)°.

Original languageEnglish
Pages (from-to)427-430
Number of pages4
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number3
Publication statusPublished - Mar 15 1999

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Deoxyribose
Sugars
Conformations
sugars
rings
Torsional stress
pyrimidines
torsion
N,N-dimethyl-5-methoxymethyl-2'-deoxycytidine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Audette, G. F., Zoghaib, W. M., Gupta, S. V., Quail, J. W., & Delbaere, L. T. J. (1999). N,N-Dimethyl-5-methoxymethyl-2′-deoxycytidine. Acta Crystallographica Section C: Crystal Structure Communications, 55(3), 427-430.

N,N-Dimethyl-5-methoxymethyl-2′-deoxycytidine. / Audette, Gerald F.; Zoghaib, Wajdi M.; Gupta, Sagar V.; Quail, J. Wilson; Delbaere, Louis T J.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 55, No. 3, 15.03.1999, p. 427-430.

Research output: Contribution to journalArticle

Audette, GF, Zoghaib, WM, Gupta, SV, Quail, JW & Delbaere, LTJ 1999, 'N,N-Dimethyl-5-methoxymethyl-2′-deoxycytidine', Acta Crystallographica Section C: Crystal Structure Communications, vol. 55, no. 3, pp. 427-430.
Audette, Gerald F. ; Zoghaib, Wajdi M. ; Gupta, Sagar V. ; Quail, J. Wilson ; Delbaere, Louis T J. / N,N-Dimethyl-5-methoxymethyl-2′-deoxycytidine. In: Acta Crystallographica Section C: Crystal Structure Communications. 1999 ; Vol. 55, No. 3. pp. 427-430.
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AU - Delbaere, Louis T J

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