N,N-dimethyl-5-methoxymethyl-2'-deoxycytidine.

G. F. Audette; W. M. Zoghaib; S. V. Gupta; J. W. Quail; L. T. Delbaere

N,N-dimethyl-5-methoxymethyl-2'-deoxycytidine.

G. F. Audette^*, W. M. Zoghaib, S. V. Gupta, J. W. Quail, L. T. Delbaere

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C13H21N3O5, the pyrimidine ring adopts the antiperiplanar (-ap) conformation [chi = 193.54 (19) degrees]. The deoxyribose sugar ring has the C2'-exo-C3'-endo (2T3) twist conformation. The pseudo-rotational parameters of the deoxyribose sugar ring are P = 6.83 (2) degrees and Tm = 38.27 (2) degrees. The exocyclic side chain at C5' has the g+ conformation [gamma = 47.7 (3) degrees]. The 5-methoxymethyl group is distal to the deoxyribose sugar ring, with a C6-C5-C52-O52 torsion angle of -91.9 (3) degrees.

Original language	English
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Publication status	Published - Mar 15 1999

ASJC Scopus subject areas

Condensed Matter Physics
Structural Biology

Cite this

@article{5e119c780d7c4cdf83f1623d039c10d7,

title = "N,N-dimethyl-5-methoxymethyl-2'-deoxycytidine.",

abstract = "In the title compound, C13H21N3O5, the pyrimidine ring adopts the antiperiplanar (-ap) conformation [chi = 193.54 (19) degrees]. The deoxyribose sugar ring has the C2'-exo-C3'-endo (2T3) twist conformation. The pseudo-rotational parameters of the deoxyribose sugar ring are P = 6.83 (2) degrees and Tm = 38.27 (2) degrees. The exocyclic side chain at C5' has the g+ conformation [gamma = 47.7 (3) degrees]. The 5-methoxymethyl group is distal to the deoxyribose sugar ring, with a C6-C5-C52-O52 torsion angle of -91.9 (3) degrees.",

author = "Audette, {G. F.} and Zoghaib, {W. M.} and Gupta, {S. V.} and Quail, {J. W.} and Delbaere, {L. T.}",

year = "1999",

month = mar,

day = "15",

language = "English",

volume = "55",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - N,N-dimethyl-5-methoxymethyl-2'-deoxycytidine.

AU - Audette, G. F.

AU - Zoghaib, W. M.

AU - Gupta, S. V.

AU - Quail, J. W.

AU - Delbaere, L. T.

PY - 1999/3/15

Y1 - 1999/3/15

N2 - In the title compound, C13H21N3O5, the pyrimidine ring adopts the antiperiplanar (-ap) conformation [chi = 193.54 (19) degrees]. The deoxyribose sugar ring has the C2'-exo-C3'-endo (2T3) twist conformation. The pseudo-rotational parameters of the deoxyribose sugar ring are P = 6.83 (2) degrees and Tm = 38.27 (2) degrees. The exocyclic side chain at C5' has the g+ conformation [gamma = 47.7 (3) degrees]. The 5-methoxymethyl group is distal to the deoxyribose sugar ring, with a C6-C5-C52-O52 torsion angle of -91.9 (3) degrees.

AB - In the title compound, C13H21N3O5, the pyrimidine ring adopts the antiperiplanar (-ap) conformation [chi = 193.54 (19) degrees]. The deoxyribose sugar ring has the C2'-exo-C3'-endo (2T3) twist conformation. The pseudo-rotational parameters of the deoxyribose sugar ring are P = 6.83 (2) degrees and Tm = 38.27 (2) degrees. The exocyclic side chain at C5' has the g+ conformation [gamma = 47.7 (3) degrees]. The 5-methoxymethyl group is distal to the deoxyribose sugar ring, with a C6-C5-C52-O52 torsion angle of -91.9 (3) degrees.

UR - http://www.scopus.com/inward/record.url?scp=0033558622&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033558622&partnerID=8YFLogxK

M3 - Article

C2 - 10220872

SN - 0108-2701

VL - 55

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

N,N-dimethyl-5-methoxymethyl-2'-deoxycytidine.

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this