Molecular structure of [MnIIIL2]- [H 2L = N-(3,5-dichloro-2-hydroxybenzyl)glycine]: Evidence for a pseudo-Jahn-Teller compression

Musa S. Shongwe, Masahiro Mikuriya, Eric W. Ainscough, Andrew M. Brodie

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Abstract

Reaction of 2 equivalents of the deprotonated ligand, L2-, with manganese(II) under ambient conditions involves one-electron oxidation of the latter to afford the title complex; a single-crystal X-ray diffraction study of this heteroleptic complex has shown the MnIII ion to be in a compressed rhombic octahedral environment in accordance with a pseudo-Jahn-Teller compression.

Original languageEnglish
Pages (from-to)887-888
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number7
DOIs
Publication statusPublished - 1994

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ASJC Scopus subject areas

  • Molecular Medicine

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