TY - JOUR
T1 - Molecular structure of [MnIIIL2]- [H 2L = N-(3,5-dichloro-2-hydroxybenzyl)glycine]
T2 - Evidence for a pseudo-Jahn-Teller compression
AU - Shongwe, Musa S.
AU - Mikuriya, Masahiro
AU - Ainscough, Eric W.
AU - Brodie, Andrew M.
PY - 1994
Y1 - 1994
N2 - Reaction of 2 equivalents of the deprotonated ligand, L2-, with manganese(II) under ambient conditions involves one-electron oxidation of the latter to afford the title complex; a single-crystal X-ray diffraction study of this heteroleptic complex has shown the MnIII ion to be in a compressed rhombic octahedral environment in accordance with a pseudo-Jahn-Teller compression.
AB - Reaction of 2 equivalents of the deprotonated ligand, L2-, with manganese(II) under ambient conditions involves one-electron oxidation of the latter to afford the title complex; a single-crystal X-ray diffraction study of this heteroleptic complex has shown the MnIII ion to be in a compressed rhombic octahedral environment in accordance with a pseudo-Jahn-Teller compression.
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U2 - 10.1039/C39940000887
DO - 10.1039/C39940000887
M3 - Article
AN - SCOPUS:37049088494
SN - 0022-4936
SP - 887
EP - 888
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 7
ER -