Molecular structure of [MnIIIL2]- [H 2L = N-(3,5-dichloro-2-hydroxybenzyl)glycine]: Evidence for a pseudo-Jahn-Teller compression

Musa S. Shongwe, Masahiro Mikuriya, Eric W. Ainscough, Andrew M. Brodie

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Reaction of 2 equivalents of the deprotonated ligand, L2-, with manganese(II) under ambient conditions involves one-electron oxidation of the latter to afford the title complex; a single-crystal X-ray diffraction study of this heteroleptic complex has shown the MnIII ion to be in a compressed rhombic octahedral environment in accordance with a pseudo-Jahn-Teller compression.

Original languageEnglish
Pages (from-to)887-888
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number7
DOIs
Publication statusPublished - 1994

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Manganese
Molecular Structure
X-Ray Diffraction
Glycine
Molecular structure
Amino acids
Compaction
Ligands
Single crystals
Electrons
Ions
X ray diffraction
Oxidation

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Molecular structure of [MnIIIL2]- [H 2L = N-(3,5-dichloro-2-hydroxybenzyl)glycine] : Evidence for a pseudo-Jahn-Teller compression. / Shongwe, Musa S.; Mikuriya, Masahiro; Ainscough, Eric W.; Brodie, Andrew M.

In: Journal of the Chemical Society, Chemical Communications, No. 7, 1994, p. 887-888.

Research output: Contribution to journalArticle

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