Metal-catalyzed [3+2] cycloadditions of azomethine imines

Uroš Grošelj; Jurij Svete; Hamad Al Mamari; Franc Požgan; Bogdan Štefane

doi:10.1007/s10593-018-2258-2

Metal-catalyzed [3+2] cycloadditions of azomethine imines

Uroš Grošelj, Jurij Svete, Hamad Al Mamari, Franc Požgan, Bogdan Štefane^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Review article › peer-review

18 Citations (Scopus)

Abstract

[Figure not available: see fulltext.] In the last decade, metal-catalyzed [3+2] cycloadditions of azomethine imines have emerged as a regioselective and stereoselective method for the synthesis of pyrazolidines and pyrazolines. A considerable number of asymmetric reactions proved the viability of metalcatalyzed [3+2] cycloadditions of azomethine imines for the synthesis of nonracemic cycloadducts. This review covers around 50 examples of title reactions that have been published since 2002.

Original language	English
Pages (from-to)	214-240
Number of pages	27
Journal	Chemistry of Heterocyclic Compounds
Volume	54
Issue number	3
DOIs	https://doi.org/10.1007/s10593-018-2258-2
Publication status	Published - Mar 1 2018

Keywords

azomethine imines
catalysis
cyclization
pyrazolines
transition metals
[3+2] cycloadditions

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1007/s10593-018-2258-2

Cite this

@article{c8b10ed393ef479d83fa0b763397fdcb,

title = "Metal-catalyzed [3+2] cycloadditions of azomethine imines",

abstract = "[Figure not available: see fulltext.] In the last decade, metal-catalyzed [3+2] cycloadditions of azomethine imines have emerged as a regioselective and stereoselective method for the synthesis of pyrazolidines and pyrazolines. A considerable number of asymmetric reactions proved the viability of metalcatalyzed [3+2] cycloadditions of azomethine imines for the synthesis of nonracemic cycloadducts. This review covers around 50 examples of title reactions that have been published since 2002.",

keywords = "azomethine imines, catalysis, cyclization, pyrazolines, transition metals, [3+2] cycloadditions",

author = "Uro{\v s} Gro{\v s}elj and Jurij Svete and {Al Mamari}, Hamad and Franc Po{\v z}gan and Bogdan {\v S}tefane",

year = "2018",

month = mar,

day = "1",

doi = "10.1007/s10593-018-2258-2",

language = "English",

volume = "54",

pages = "214--240",

journal = "Chemistry of Heterocyclic Compounds",

issn = "0009-3122",

publisher = "Springer New York",

number = "3",

}

TY - JOUR

T1 - Metal-catalyzed [3+2] cycloadditions of azomethine imines

AU - Grošelj, Uroš

AU - Svete, Jurij

AU - Al Mamari, Hamad

AU - Požgan, Franc

AU - Štefane, Bogdan

PY - 2018/3/1

Y1 - 2018/3/1

N2 - [Figure not available: see fulltext.] In the last decade, metal-catalyzed [3+2] cycloadditions of azomethine imines have emerged as a regioselective and stereoselective method for the synthesis of pyrazolidines and pyrazolines. A considerable number of asymmetric reactions proved the viability of metalcatalyzed [3+2] cycloadditions of azomethine imines for the synthesis of nonracemic cycloadducts. This review covers around 50 examples of title reactions that have been published since 2002.

AB - [Figure not available: see fulltext.] In the last decade, metal-catalyzed [3+2] cycloadditions of azomethine imines have emerged as a regioselective and stereoselective method for the synthesis of pyrazolidines and pyrazolines. A considerable number of asymmetric reactions proved the viability of metalcatalyzed [3+2] cycloadditions of azomethine imines for the synthesis of nonracemic cycloadducts. This review covers around 50 examples of title reactions that have been published since 2002.

KW - azomethine imines

KW - catalysis

KW - cyclization

KW - pyrazolines

KW - transition metals

KW - [3+2] cycloadditions

UR - http://www.scopus.com/inward/record.url?scp=85047192922&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85047192922&partnerID=8YFLogxK

U2 - 10.1007/s10593-018-2258-2

DO - 10.1007/s10593-018-2258-2

M3 - Review article

AN - SCOPUS:85047192922

SN - 0009-3122

VL - 54

SP - 214

EP - 240

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

IS - 3

ER -

Metal-catalyzed [3+2] cycloadditions of azomethine imines

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this