TY - JOUR
T1 - Membrane based reactors for sustainable treatment of Coronopus didymus L. by developing Iodine doped potassium oxide Catalyst under Dynamic conditions
AU - Chaudhry, Bisha
AU - Akhtar, Muhammad Saeed
AU - Ahmad, Mushtaq
AU - Munir, Mamoona
AU - Zafar, Muhammad
AU - Alhajeri, Nawaf S.
AU - Al-Muhtaseb, Ala'a H.
AU - Ahmad, Zubair
AU - Hasan, Mudassir
AU - Bokhari, Awais
N1 - Funding Information:
This work was supported by the Deanship of Scientific Research at King Khalid University , Abha-KSA, for funding this research through General Research Project under grant number ( R.G.P. 2/189/43 ). This research has also been supported by the project Sustainable Process Integration Laboratory – SPIL , funded as project No. CZ.02.1.01/0.0/0.0/15_003/0000456 , the Operational Programme Research, Development and Education of the Czech Ministry of Education, Youth and Sports by EU European Structural and Investment Funds , Operational Programme Research, Development and Education .
Publisher Copyright:
© 2022 Elsevier Ltd
PY - 2022/9
Y1 - 2022/9
N2 - Green nano-technology together with the availability of eco-friendly and alternative sources are the promising candidates to combat environment deteriorations and energy clutches globally. The current work focuses on the synthesis and application of newly synthesized nano catalyst of Iodine doped Potassium oxide I (K2O) for producing sustainable biodiesel from novel non-edible seed oils of Coronopus didymus L. using membrane based contactor to avoid emulsification and phase separation issues. Highest biodiesel yield (97.03%) was obtained under optimum conditions of 12:1 methanol to oil ratio, reaction temperature of 65 °C for 150 min with the 1.0 wt% catalyst concentration. The lately synthesized, environment friendly and recyclable Iodine doped Potassium oxide K (IO)2 catalyst was synthesized via chemical method followed by characterization via advanced techniques including EDX, XRD, FTIR and SEM analysis. The catalyst was proved to be stable and efficient with the reusability of five times in transesterification reaction. These analysis have reported the sustainability, stability and good quality of biodiesel from seed oil of Coronopus didymus L. using efficient Iodine doped potassium oxide catalyst. Thus, non-edible, environment friendly and novel Coronopus didymus L. seeds and their extracted oil along with Iodine doped potassium oxide catalyst seems to be highly affective, sustainable and better alternative source to the future biodiesel industry. Also, by altering the reaction equilibrium and lowering the purification phases of the process, these studies show the potential of coupling transesterification and a membrane contactor.
AB - Green nano-technology together with the availability of eco-friendly and alternative sources are the promising candidates to combat environment deteriorations and energy clutches globally. The current work focuses on the synthesis and application of newly synthesized nano catalyst of Iodine doped Potassium oxide I (K2O) for producing sustainable biodiesel from novel non-edible seed oils of Coronopus didymus L. using membrane based contactor to avoid emulsification and phase separation issues. Highest biodiesel yield (97.03%) was obtained under optimum conditions of 12:1 methanol to oil ratio, reaction temperature of 65 °C for 150 min with the 1.0 wt% catalyst concentration. The lately synthesized, environment friendly and recyclable Iodine doped Potassium oxide K (IO)2 catalyst was synthesized via chemical method followed by characterization via advanced techniques including EDX, XRD, FTIR and SEM analysis. The catalyst was proved to be stable and efficient with the reusability of five times in transesterification reaction. These analysis have reported the sustainability, stability and good quality of biodiesel from seed oil of Coronopus didymus L. using efficient Iodine doped potassium oxide catalyst. Thus, non-edible, environment friendly and novel Coronopus didymus L. seeds and their extracted oil along with Iodine doped potassium oxide catalyst seems to be highly affective, sustainable and better alternative source to the future biodiesel industry. Also, by altering the reaction equilibrium and lowering the purification phases of the process, these studies show the potential of coupling transesterification and a membrane contactor.
KW - Catalyst
KW - Membrane
KW - Non-edible oil seeds
KW - Reusability
KW - Sustainable development
UR - http://www.scopus.com/inward/record.url?scp=85131446173&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85131446173&partnerID=8YFLogxK
U2 - 10.1016/j.chemosphere.2022.135138
DO - 10.1016/j.chemosphere.2022.135138
M3 - Article
C2 - 35636597
AN - SCOPUS:85131446173
SN - 0045-6535
VL - 303
JO - Chemosphere
JF - Chemosphere
M1 - 135138
ER -