Magnetic properties of Ba2 HoSbO6 with a frustrated lattice geometry

S. Calder, X. Ke, F. Bert, A. Amato, C. Baines, C. Carboni, R. J. Cava, A. Daoud-Aladine, P. Deen, T. Fennell, A. D. Hillier, H. Karunadasa, J. W. Taylor, P. Mendels, P. Schiffer, S. T. Bramwell

Research output: Contribution to journalArticle

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Abstract

The study of geometrically frustrated magnets with unusual crystal field ground states offers the possibility of discovering new aspects of the physics of cooperative paramagnetic states. In the rare-earth double perovskite Ba2 HoSbO6 the Ho3+ ions occupy a face-centered cubic lattice, which frustrates near-neighbor antiferromagnetic coupling. We present a systematic experimental study of the system using dc magnetization, heat capacity, muon-spin relaxation, inelastic neutron scattering, neutron powder diffraction, and neutron polarization analysis. The bulk measurements at first point to spin liquid behavior, but the microscopic measurements indicate that this system is an example of a "nonmagnetic doublet" crystal field ground state, with low-lying excited states. Our measurements are interpreted using crystal field theory of Ho3+, including hyperfine coupling. We find that exchange and dipolar coupling are weak in this particular system and that the "mock spin liquid" behavior in fact reflects the unusual properties of the nonmagnetic doublet.

Original languageEnglish
Article number064425
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume81
Issue number6
DOIs
Publication statusPublished - Feb 23 2010

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crystal field theory
Magnetic properties
magnetic properties
Ground state
Crystals
Geometry
geometry
neutrons
face centered cubic lattices
Inelastic neutron scattering
Neutron powder diffraction
ground state
Liquids
liquids
Excited states
Perovskite
Rare earths
Specific heat
Magnets
muons

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

Cite this

Magnetic properties of Ba2 HoSbO6 with a frustrated lattice geometry. / Calder, S.; Ke, X.; Bert, F.; Amato, A.; Baines, C.; Carboni, C.; Cava, R. J.; Daoud-Aladine, A.; Deen, P.; Fennell, T.; Hillier, A. D.; Karunadasa, H.; Taylor, J. W.; Mendels, P.; Schiffer, P.; Bramwell, S. T.

In: Physical Review B - Condensed Matter and Materials Physics, Vol. 81, No. 6, 064425, 23.02.2010.

Research output: Contribution to journalArticle

Calder, S, Ke, X, Bert, F, Amato, A, Baines, C, Carboni, C, Cava, RJ, Daoud-Aladine, A, Deen, P, Fennell, T, Hillier, AD, Karunadasa, H, Taylor, JW, Mendels, P, Schiffer, P & Bramwell, ST 2010, 'Magnetic properties of Ba2 HoSbO6 with a frustrated lattice geometry', Physical Review B - Condensed Matter and Materials Physics, vol. 81, no. 6, 064425. https://doi.org/10.1103/PhysRevB.81.064425
Calder, S. ; Ke, X. ; Bert, F. ; Amato, A. ; Baines, C. ; Carboni, C. ; Cava, R. J. ; Daoud-Aladine, A. ; Deen, P. ; Fennell, T. ; Hillier, A. D. ; Karunadasa, H. ; Taylor, J. W. ; Mendels, P. ; Schiffer, P. ; Bramwell, S. T. / Magnetic properties of Ba2 HoSbO6 with a frustrated lattice geometry. In: Physical Review B - Condensed Matter and Materials Physics. 2010 ; Vol. 81, No. 6.
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