Influence of the doping of Ti4+ ions on electrical and magnetic properties of Mn1+xFe2-2xTixO4 ferrite

A. M M Farea, Shalendra Kumar, Khalid Mujasam Batoo, Ali Yousef, Chan Gyu Lee, Alimuddin

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

ac conductivity and magnetic behaviour have been studied for a series of polycrystalline ferrite with general formula Mn1-xFe2-2xTixO4, (0 ≤ x ≤ 0.5), prepared using a conventional solid-state reaction technique. The results of ac conductivity show that σac increases as the frequency and the temperature increase; whereas it decreases as Ti content increases except for a sample x = 0.1. The values of activation energies Ef for conduction process are determined from Arrhenius plots, and the variations of these activation energies as a function of composition have been discussed. The conduction mechanism used in present study have been discussed in the light of electron exchange between Fe2 and Fe3 ions and hole hopping between Mn+3 and Mn+2 ions at the octahedral B-sites. It observed that the saturation magnetization decreases with increase Ti4+ substitution, which is explained by the weakening of the exchange in the system according to Neel's molecular field model.

Original languageEnglish
Pages (from-to)451-457
Number of pages7
JournalJournal of Alloys and Compounds
Volume469
Issue number1-2
DOIs
Publication statusPublished - Feb 5 2009

Fingerprint

Ferrite
Magnetic properties
Electric properties
Activation energy
Doping (additives)
Ions
Arrhenius plots
Saturation magnetization
Solid state reactions
Ion exchange
Substitution reactions
Electrons
Chemical analysis
Temperature

Keywords

  • ac conductivity
  • Ferrite
  • Magnetization

ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • Materials Chemistry
  • Metals and Alloys

Cite this

Influence of the doping of Ti4+ ions on electrical and magnetic properties of Mn1+xFe2-2xTixO4 ferrite. / Farea, A. M M; Kumar, Shalendra; Batoo, Khalid Mujasam; Yousef, Ali; Lee, Chan Gyu; Alimuddin.

In: Journal of Alloys and Compounds, Vol. 469, No. 1-2, 05.02.2009, p. 451-457.

Research output: Contribution to journalArticle

Farea, A. M M ; Kumar, Shalendra ; Batoo, Khalid Mujasam ; Yousef, Ali ; Lee, Chan Gyu ; Alimuddin. / Influence of the doping of Ti4+ ions on electrical and magnetic properties of Mn1+xFe2-2xTixO4 ferrite. In: Journal of Alloys and Compounds. 2009 ; Vol. 469, No. 1-2. pp. 451-457.
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AB - ac conductivity and magnetic behaviour have been studied for a series of polycrystalline ferrite with general formula Mn1-xFe2-2xTixO4, (0 ≤ x ≤ 0.5), prepared using a conventional solid-state reaction technique. The results of ac conductivity show that σac increases as the frequency and the temperature increase; whereas it decreases as Ti content increases except for a sample x = 0.1. The values of activation energies Ef for conduction process are determined from Arrhenius plots, and the variations of these activation energies as a function of composition have been discussed. The conduction mechanism used in present study have been discussed in the light of electron exchange between Fe2 and Fe3 ions and hole hopping between Mn+3 and Mn+2 ions at the octahedral B-sites. It observed that the saturation magnetization decreases with increase Ti4+ substitution, which is explained by the weakening of the exchange in the system according to Neel's molecular field model.

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