Impact of Molecular Weight on the Thermal Stability and the Miscibility of Poly(ε-caprolactone)/Polystyrene Binary Blends

Al Mamun, S. M.Mujibur Rahman, Sébastien Roland, Rizwan Mahmood

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Poly(ε-caprolactone) (PCL) and two different molecular weight (6K and 650K) of polystyrene (PS) were mixed in solution to prepare binary blends of PCL/PS with various compositions. The impact of the molecular weight of PS in the blends was studied on thermal stability and miscibility by the thermogravimetric analysis (TGA) and the differential scanning calorimetry (DSC) method. The TGA results under dynamic conditions in an inert atmosphere show that the thermal stability of the blends depends on the length of PS molecules. The increase of the low molecular weight PS into the PCL/PS blend reduces the thermal stability while the high molecular weight PS improves the thermal stability. The crystallization peak temperature, enthalpy, and crystallinity of the blends are found molecular weight dependent; these parameters with blend compositions deviate from linearity of additive law for low molecular weight PS, while they do follow the additive law for high molecular weight PS. A significant melting point depression of PCL crystals with composition was observed for the blends with the incorporation of the low molecular weight PS, while the no significant melting temperature depression was observed for the high molecular weight PS. The experimental results clearly indicate that in the PCL/PS blends, the thermal stability and the interaction between the neat components strongly depend on the molecular weight of the PS.

Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalJournal of Polymers and the Environment
DOIs
Publication statusAccepted/In press - Apr 19 2018

Fingerprint

Polystyrenes
Thermodynamic stability
Solubility
Molecular weight
polycaprolactone
Melting point
Thermogravimetric analysis
Chemical analysis
Crystallization
Differential scanning calorimetry
Enthalpy

Keywords

  • Miscibility
  • Molecular weight effect
  • Poly(ε-caprolactone)
  • Polystyrene
  • Thermal stability

ASJC Scopus subject areas

  • Environmental Engineering
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Impact of Molecular Weight on the Thermal Stability and the Miscibility of Poly(ε-caprolactone)/Polystyrene Binary Blends. / Mamun, Al; Rahman, S. M.Mujibur; Roland, Sébastien; Mahmood, Rizwan.

In: Journal of Polymers and the Environment, 19.04.2018, p. 1-9.

Research output: Contribution to journalArticle

@article{42742a980e4b4d1f8795997107406ecb,
title = "Impact of Molecular Weight on the Thermal Stability and the Miscibility of Poly(ε-caprolactone)/Polystyrene Binary Blends",
abstract = "Poly(ε-caprolactone) (PCL) and two different molecular weight (6K and 650K) of polystyrene (PS) were mixed in solution to prepare binary blends of PCL/PS with various compositions. The impact of the molecular weight of PS in the blends was studied on thermal stability and miscibility by the thermogravimetric analysis (TGA) and the differential scanning calorimetry (DSC) method. The TGA results under dynamic conditions in an inert atmosphere show that the thermal stability of the blends depends on the length of PS molecules. The increase of the low molecular weight PS into the PCL/PS blend reduces the thermal stability while the high molecular weight PS improves the thermal stability. The crystallization peak temperature, enthalpy, and crystallinity of the blends are found molecular weight dependent; these parameters with blend compositions deviate from linearity of additive law for low molecular weight PS, while they do follow the additive law for high molecular weight PS. A significant melting point depression of PCL crystals with composition was observed for the blends with the incorporation of the low molecular weight PS, while the no significant melting temperature depression was observed for the high molecular weight PS. The experimental results clearly indicate that in the PCL/PS blends, the thermal stability and the interaction between the neat components strongly depend on the molecular weight of the PS.",
keywords = "Miscibility, Molecular weight effect, Poly(ε-caprolactone), Polystyrene, Thermal stability",
author = "Al Mamun and Rahman, {S. M.Mujibur} and S{\'e}bastien Roland and Rizwan Mahmood",
year = "2018",
month = "4",
day = "19",
doi = "10.1007/s10924-018-1236-1",
language = "English",
pages = "1--9",
journal = "Journal of Polymers and the Environment",
issn = "1566-2543",
publisher = "Springer New York",

}

TY - JOUR

T1 - Impact of Molecular Weight on the Thermal Stability and the Miscibility of Poly(ε-caprolactone)/Polystyrene Binary Blends

AU - Mamun, Al

AU - Rahman, S. M.Mujibur

AU - Roland, Sébastien

AU - Mahmood, Rizwan

PY - 2018/4/19

Y1 - 2018/4/19

N2 - Poly(ε-caprolactone) (PCL) and two different molecular weight (6K and 650K) of polystyrene (PS) were mixed in solution to prepare binary blends of PCL/PS with various compositions. The impact of the molecular weight of PS in the blends was studied on thermal stability and miscibility by the thermogravimetric analysis (TGA) and the differential scanning calorimetry (DSC) method. The TGA results under dynamic conditions in an inert atmosphere show that the thermal stability of the blends depends on the length of PS molecules. The increase of the low molecular weight PS into the PCL/PS blend reduces the thermal stability while the high molecular weight PS improves the thermal stability. The crystallization peak temperature, enthalpy, and crystallinity of the blends are found molecular weight dependent; these parameters with blend compositions deviate from linearity of additive law for low molecular weight PS, while they do follow the additive law for high molecular weight PS. A significant melting point depression of PCL crystals with composition was observed for the blends with the incorporation of the low molecular weight PS, while the no significant melting temperature depression was observed for the high molecular weight PS. The experimental results clearly indicate that in the PCL/PS blends, the thermal stability and the interaction between the neat components strongly depend on the molecular weight of the PS.

AB - Poly(ε-caprolactone) (PCL) and two different molecular weight (6K and 650K) of polystyrene (PS) were mixed in solution to prepare binary blends of PCL/PS with various compositions. The impact of the molecular weight of PS in the blends was studied on thermal stability and miscibility by the thermogravimetric analysis (TGA) and the differential scanning calorimetry (DSC) method. The TGA results under dynamic conditions in an inert atmosphere show that the thermal stability of the blends depends on the length of PS molecules. The increase of the low molecular weight PS into the PCL/PS blend reduces the thermal stability while the high molecular weight PS improves the thermal stability. The crystallization peak temperature, enthalpy, and crystallinity of the blends are found molecular weight dependent; these parameters with blend compositions deviate from linearity of additive law for low molecular weight PS, while they do follow the additive law for high molecular weight PS. A significant melting point depression of PCL crystals with composition was observed for the blends with the incorporation of the low molecular weight PS, while the no significant melting temperature depression was observed for the high molecular weight PS. The experimental results clearly indicate that in the PCL/PS blends, the thermal stability and the interaction between the neat components strongly depend on the molecular weight of the PS.

KW - Miscibility

KW - Molecular weight effect

KW - Poly(ε-caprolactone)

KW - Polystyrene

KW - Thermal stability

UR - http://www.scopus.com/inward/record.url?scp=85045769213&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85045769213&partnerID=8YFLogxK

U2 - 10.1007/s10924-018-1236-1

DO - 10.1007/s10924-018-1236-1

M3 - Article

SP - 1

EP - 9

JO - Journal of Polymers and the Environment

JF - Journal of Polymers and the Environment

SN - 1566-2543

ER -