High-Performance Photocatalytic Hydrogen Production and Degradation of Levofloxacin by Wide Spectrum-Responsive Ag/Fe3O4 Bridged SrTiO3/g-C3N4 Plasmonic Nanojunctions

Joint Effect of Ag and Fe3O4

Amit Kumar, Anamika Rana, Gaurav Sharma, Mu Naushad, Ala Al-Muhtaseb, Changsheng Guo, Ana Iglesias-Juez, Florian J. Stadler

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Highly photoresponsive semiconductor photocatalysis for energy and environmental applications require judicious choice and optimization of semiconductor interfaces for wide spectral capabilities. This work aims at rational designing of highly active SrTiO3/g-C3N4 junctions bridged with Ag/Fe3O4 nanoparticles for utilizing Z-scheme transfer and surface plasmon resonance effect of Ag augmented by iron oxide. The SrTiO3/(Ag/Fe3O4)/g-C3N4 (SFC) catalyst was employed for photocatalytic hydrogen production and photodegradation of levofloxacin (LFC; 20 mg/L) under UV, visible, near infra-red, and natural solar light exhibiting high performance. Under visible light (<780 nm), SFC-3 sample (30 wt % g-C3N4 and 3% Ag/Fe3O4) shows a H2 evolution of 2008 μmol g-1 h-1 which is ∼14 times that of bare g-C3N4. In addition, 99.3% removal of LFC was degraded in 90 min under visible light with retention of activity under sun. The inherent topological properties, complete, higher charge separation, and reduced recombination allowed this catalyst for a high photocatalytic response which was proved by UV-diffuse reflectance spectroscopy, photoluminescence, electrochemical impedance spectroscopy, and photocurrent response measurements. Scavenging experiments and electron spin resonance analysis reveal that the mechanism shifts from a dual charge transfer in case of binary junction to essential Z-scheme with incorporation of Ag/Fe3O4. Both O2 - and OH are main active radicals in visible light, whereas O2 - majorly participate under UV. The synergistic effect of SrTiO3, g-C3N4, and plasmon resonance of Ag/Fe3O4 not only improves light response and reduce recombination but also enhances the redox-ability of charge carriers. A H2 production mechanism and LFC degradation pathway (degradation, defluorination, and hydrolysis) has been predicted. This work paves a way for development of photocatalysts working in practical conditions for pollution and energy issues.

Original languageEnglish
Pages (from-to)40474-40490
Number of pages17
JournalACS Applied Materials and Interfaces
Volume10
Issue number47
DOIs
Publication statusPublished - Nov 28 2018

Fingerprint

Levofloxacin
Hydrogen production
Degradation
Semiconductor materials
Catalysts
Photoluminescence spectroscopy
Photocatalysis
Scavenging
Photodegradation
Surface plasmon resonance
Photocatalysts
Charge carriers
Photocurrents
Electrochemical impedance spectroscopy
Iron oxides
Sun
Paramagnetic resonance
Charge transfer
Hydrolysis
Pollution

Keywords

  • graphitic carbon nitride
  • hetero-junction
  • hydrogen production
  • pharmaceutical effluents
  • plasmonic Ag
  • strontium titanate

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

High-Performance Photocatalytic Hydrogen Production and Degradation of Levofloxacin by Wide Spectrum-Responsive Ag/Fe3O4 Bridged SrTiO3/g-C3N4 Plasmonic Nanojunctions : Joint Effect of Ag and Fe3O4. / Kumar, Amit; Rana, Anamika; Sharma, Gaurav; Naushad, Mu; Al-Muhtaseb, Ala; Guo, Changsheng; Iglesias-Juez, Ana; Stadler, Florian J.

In: ACS Applied Materials and Interfaces, Vol. 10, No. 47, 28.11.2018, p. 40474-40490.

Research output: Contribution to journalArticle

Kumar, Amit ; Rana, Anamika ; Sharma, Gaurav ; Naushad, Mu ; Al-Muhtaseb, Ala ; Guo, Changsheng ; Iglesias-Juez, Ana ; Stadler, Florian J. / High-Performance Photocatalytic Hydrogen Production and Degradation of Levofloxacin by Wide Spectrum-Responsive Ag/Fe3O4 Bridged SrTiO3/g-C3N4 Plasmonic Nanojunctions : Joint Effect of Ag and Fe3O4. In: ACS Applied Materials and Interfaces. 2018 ; Vol. 10, No. 47. pp. 40474-40490.
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abstract = "Highly photoresponsive semiconductor photocatalysis for energy and environmental applications require judicious choice and optimization of semiconductor interfaces for wide spectral capabilities. This work aims at rational designing of highly active SrTiO3/g-C3N4 junctions bridged with Ag/Fe3O4 nanoparticles for utilizing Z-scheme transfer and surface plasmon resonance effect of Ag augmented by iron oxide. The SrTiO3/(Ag/Fe3O4)/g-C3N4 (SFC) catalyst was employed for photocatalytic hydrogen production and photodegradation of levofloxacin (LFC; 20 mg/L) under UV, visible, near infra-red, and natural solar light exhibiting high performance. Under visible light (<780 nm), SFC-3 sample (30 wt {\%} g-C3N4 and 3{\%} Ag/Fe3O4) shows a H2 evolution of 2008 μmol g-1 h-1 which is ∼14 times that of bare g-C3N4. In addition, 99.3{\%} removal of LFC was degraded in 90 min under visible light with retention of activity under sun. The inherent topological properties, complete, higher charge separation, and reduced recombination allowed this catalyst for a high photocatalytic response which was proved by UV-diffuse reflectance spectroscopy, photoluminescence, electrochemical impedance spectroscopy, and photocurrent response measurements. Scavenging experiments and electron spin resonance analysis reveal that the mechanism shifts from a dual charge transfer in case of binary junction to essential Z-scheme with incorporation of Ag/Fe3O4. Both •O2 - and •OH are main active radicals in visible light, whereas •O2 - majorly participate under UV. The synergistic effect of SrTiO3, g-C3N4, and plasmon resonance of Ag/Fe3O4 not only improves light response and reduce recombination but also enhances the redox-ability of charge carriers. A H2 production mechanism and LFC degradation pathway (degradation, defluorination, and hydrolysis) has been predicted. This work paves a way for development of photocatalysts working in practical conditions for pollution and energy issues.",
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