Heterogeneous photocatalytic degradation of chlorophenols over Ag-TiO 2 nano particles in an aqueous suspension

Selvaraj Rengaraj, Jei Won Yeon, Xiang Zhong Li, Yongju Jung, Won Ho Kim

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

In the present work, TiO2 and Ag-TiO2 catalysts were prepared by an ultrasonic assisted sol-gel method. The physico-chemical characteristics studies of the newly synthesized catalysts were carried out by XRD, TEM, EDX, XPS, UV-Visible absorption spectra and an optical ellipsometry. In order to find out the optical absorption properties of the catalysts, theoretical simulations have been carried out by using the Tauc-Lorentz oscillator model. Photodegradation and mineralisation of the chlorophenols were confirmed by the HPLC and TOC measurements. The rate of a mineralisation trend was observed in the order of P <2-CP <2,4-DCP <2,6-DCP <4-CP <2,4,6-TCP by using the Ag-TiO2 catalyst. The concentration of the main aromatic intermediate products was considerably lower for the Ag-TiO2 photocatalysts than for pure TiO2. This experiment demonstrated that the presence of Ag on TiO2 catalysts could enhance the photocatalytic oxidation of chlorophenols in an aqueous suspension. It was found that the degradation of the chlorphenols by these catalysts followed the pseudo- first order kinetic model.

Original languageEnglish
Title of host publicationSolid State Phenomena
PublisherTrans Tech Publications Ltd
Pages1745-1748
Number of pages4
Volume124-126
EditionPART 2
ISBN (Print)3908451310, 9783908451310
Publication statusPublished - 2007
EventIUMRS International Conference in Asia 2006, IUMRS-ICA 2006 - Jeju, Korea, Republic of
Duration: Sep 10 2006Sep 14 2006

Publication series

NameSolid State Phenomena
NumberPART 2
Volume124-126
ISSN (Print)10120394

Other

OtherIUMRS International Conference in Asia 2006, IUMRS-ICA 2006
CountryKorea, Republic of
CityJeju
Period9/10/069/14/06

Keywords

  • Ag deposition
  • Chlorophenols
  • Photodegradation
  • Sol-gel
  • UV light

ASJC Scopus subject areas

  • Materials Science(all)
  • Physics and Astronomy (miscellaneous)
  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

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  • Cite this

    Rengaraj, S., Yeon, J. W., Li, X. Z., Jung, Y., & Kim, W. H. (2007). Heterogeneous photocatalytic degradation of chlorophenols over Ag-TiO 2 nano particles in an aqueous suspension. In Solid State Phenomena (PART 2 ed., Vol. 124-126, pp. 1745-1748). (Solid State Phenomena; Vol. 124-126, No. PART 2). Trans Tech Publications Ltd.