Glucose-based deep eutectic solvents: Physical properties

Adeeb Hayyan, Farouq S. Mjalli, Inas M. Alnashef, Yahya M. Al-Wahaibi, Talal Al-Wahaibi, Mohd Ali Hashim

Research output: Contribution to journalArticle

125 Citations (Scopus)

Abstract

Deep eutectic solvents (DESs) are considered nowadays as green ionic liquid (IL) analogues. Despite their relatively short period of introduction as a special class of ILs, they have been under an increasing emphasis by the scientific community due to their favorable properties. In the present study, a glucose based DES of choline chloride (2-hydroxyethyl-trimethylammonium chloride) with the monosaccharide sugar d-glucose anhydrous was synthesized at different molar ratios. The physical properties of density, viscosity, surface tension, refractive index, and pH were measured and analyzed as function of temperature in the practical temperature range of 298.15-358.15 K. The analysis of these physical properties revealed that these novel DESs have the potential to be utilized for several possible industrial applications involving processing and separation of food constituents, pharmaceutical applications, as well as mediums for chemical reactions.

Original languageEnglish
Pages (from-to)137-141
Number of pages5
JournalJournal of Molecular Liquids
Volume178
DOIs
Publication statusPublished - Feb 2013

Fingerprint

glucose
eutectics
Eutectics
Glucose
Physical properties
physical properties
chlorides
monosaccharides
Ionic Liquids
choline
Monosaccharides
sugars
Choline
Ionic liquids
food
Sugars
Drug products
Industrial applications
Surface tension
Chlorides

Keywords

  • Deep eutectic solvents
  • Glucose
  • Ionic liquids
  • Monosaccharides

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry

Cite this

Glucose-based deep eutectic solvents : Physical properties. / Hayyan, Adeeb; Mjalli, Farouq S.; Alnashef, Inas M.; Al-Wahaibi, Yahya M.; Al-Wahaibi, Talal; Hashim, Mohd Ali.

In: Journal of Molecular Liquids, Vol. 178, 02.2013, p. 137-141.

Research output: Contribution to journalArticle

@article{a99cbb5508264caebe9628c8ad5bcf28,
title = "Glucose-based deep eutectic solvents: Physical properties",
abstract = "Deep eutectic solvents (DESs) are considered nowadays as green ionic liquid (IL) analogues. Despite their relatively short period of introduction as a special class of ILs, they have been under an increasing emphasis by the scientific community due to their favorable properties. In the present study, a glucose based DES of choline chloride (2-hydroxyethyl-trimethylammonium chloride) with the monosaccharide sugar d-glucose anhydrous was synthesized at different molar ratios. The physical properties of density, viscosity, surface tension, refractive index, and pH were measured and analyzed as function of temperature in the practical temperature range of 298.15-358.15 K. The analysis of these physical properties revealed that these novel DESs have the potential to be utilized for several possible industrial applications involving processing and separation of food constituents, pharmaceutical applications, as well as mediums for chemical reactions.",
keywords = "Deep eutectic solvents, Glucose, Ionic liquids, Monosaccharides",
author = "Adeeb Hayyan and Mjalli, {Farouq S.} and Alnashef, {Inas M.} and Al-Wahaibi, {Yahya M.} and Talal Al-Wahaibi and Hashim, {Mohd Ali}",
year = "2013",
month = "2",
doi = "10.1016/j.molliq.2012.11.025",
language = "English",
volume = "178",
pages = "137--141",
journal = "Journal of Molecular Liquids",
issn = "0167-7322",
publisher = "Elsevier",

}

TY - JOUR

T1 - Glucose-based deep eutectic solvents

T2 - Physical properties

AU - Hayyan, Adeeb

AU - Mjalli, Farouq S.

AU - Alnashef, Inas M.

AU - Al-Wahaibi, Yahya M.

AU - Al-Wahaibi, Talal

AU - Hashim, Mohd Ali

PY - 2013/2

Y1 - 2013/2

N2 - Deep eutectic solvents (DESs) are considered nowadays as green ionic liquid (IL) analogues. Despite their relatively short period of introduction as a special class of ILs, they have been under an increasing emphasis by the scientific community due to their favorable properties. In the present study, a glucose based DES of choline chloride (2-hydroxyethyl-trimethylammonium chloride) with the monosaccharide sugar d-glucose anhydrous was synthesized at different molar ratios. The physical properties of density, viscosity, surface tension, refractive index, and pH were measured and analyzed as function of temperature in the practical temperature range of 298.15-358.15 K. The analysis of these physical properties revealed that these novel DESs have the potential to be utilized for several possible industrial applications involving processing and separation of food constituents, pharmaceutical applications, as well as mediums for chemical reactions.

AB - Deep eutectic solvents (DESs) are considered nowadays as green ionic liquid (IL) analogues. Despite their relatively short period of introduction as a special class of ILs, they have been under an increasing emphasis by the scientific community due to their favorable properties. In the present study, a glucose based DES of choline chloride (2-hydroxyethyl-trimethylammonium chloride) with the monosaccharide sugar d-glucose anhydrous was synthesized at different molar ratios. The physical properties of density, viscosity, surface tension, refractive index, and pH were measured and analyzed as function of temperature in the practical temperature range of 298.15-358.15 K. The analysis of these physical properties revealed that these novel DESs have the potential to be utilized for several possible industrial applications involving processing and separation of food constituents, pharmaceutical applications, as well as mediums for chemical reactions.

KW - Deep eutectic solvents

KW - Glucose

KW - Ionic liquids

KW - Monosaccharides

UR - http://www.scopus.com/inward/record.url?scp=84871368912&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84871368912&partnerID=8YFLogxK

U2 - 10.1016/j.molliq.2012.11.025

DO - 10.1016/j.molliq.2012.11.025

M3 - Article

AN - SCOPUS:84871368912

VL - 178

SP - 137

EP - 141

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

SN - 0167-7322

ER -