Generation of Superoxide Ion in Trihexyl (Tetradecyl) Phosphonium bis (Trifluoromethylsulfonyl) imide Room Temperature Ionic Liquid

M. Hayyan; Farouq S. Mjalli; M. A. Hashim; Inas M. AlNashef; X. M. Tan; K. L. Chooi

doi:10.3923/jas.2010.1176.1180

Generation of Superoxide Ion in Trihexyl (Tetradecyl) Phosphonium bis (Trifluoromethylsulfonyl) imide Room Temperature Ionic Liquid

M. Hayyan^*, Farouq S. Mjalli, M. A. Hashim, Inas M. AlNashef, X. M. Tan, K. L. Chooi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Superoxide ion has been generated in room temperature ionic liquid trihexyl (tetradecyl) phosphonium bis (trifluoromethylsulfonyl)imide, [P14,666][N(Tf)₂]. Cyclic voltammetry and chronoamperometry techniques were used for the electrochemical generation of O^m₂^._, while chemical generation was done by adding KO₂ to dimethylsulphoxide (DMSO). The long term stability of O₂^._ was investigated using UV/Vis spectrophotometer. It was found that the quaternary phosphonium cation, [PI 4,666]⁺ is a reasonably stable cation in the presence of 0₂^._ which indicates the possible use of these ILs for further useful applications.

Original language	English
Pages (from-to)	1176-1180
Number of pages	5
Journal	Journal of Applied Sciences
Volume	10
Issue number	12
DOIs	https://doi.org/10.3923/jas.2010.1176.1180
Publication status	Published - 2010
Externally published	Yes

Keywords

Ionic liquids
Phosphonium
Stability
Superoxide ion

ASJC Scopus subject areas

General

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10.3923/jas.2010.1176.1180

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title = "Generation of Superoxide Ion in Trihexyl (Tetradecyl) Phosphonium bis (Trifluoromethylsulfonyl) imide Room Temperature Ionic Liquid",

abstract = "Superoxide ion has been generated in room temperature ionic liquid trihexyl (tetradecyl) phosphonium bis (trifluoromethylsulfonyl)imide, [P14,666][N(Tf)2]. Cyclic voltammetry and chronoamperometry techniques were used for the electrochemical generation of Om2._, while chemical generation was done by adding KO2 to dimethylsulphoxide (DMSO). The long term stability of O2._ was investigated using UV/Vis spectrophotometer. It was found that the quaternary phosphonium cation, [PI 4,666]+ is a reasonably stable cation in the presence of 02._ which indicates the possible use of these ILs for further useful applications.",

keywords = "Ionic liquids, Phosphonium, Stability, Superoxide ion",

author = "M. Hayyan and Mjalli, {Farouq S.} and Hashim, {M. A.} and AlNashef, {Inas M.} and Tan, {X. M.} and Chooi, {K. L.}",

year = "2010",

doi = "10.3923/jas.2010.1176.1180",

language = "English",

volume = "10",

pages = "1176--1180",

journal = "Journal of Applied Sciences",

issn = "1812-5654",

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T1 - Generation of Superoxide Ion in Trihexyl (Tetradecyl) Phosphonium bis (Trifluoromethylsulfonyl) imide Room Temperature Ionic Liquid

AU - Hayyan, M.

AU - Mjalli, Farouq S.

AU - Hashim, M. A.

AU - AlNashef, Inas M.

AU - Tan, X. M.

AU - Chooi, K. L.

PY - 2010

Y1 - 2010

N2 - Superoxide ion has been generated in room temperature ionic liquid trihexyl (tetradecyl) phosphonium bis (trifluoromethylsulfonyl)imide, [P14,666][N(Tf)2]. Cyclic voltammetry and chronoamperometry techniques were used for the electrochemical generation of Om2._, while chemical generation was done by adding KO2 to dimethylsulphoxide (DMSO). The long term stability of O2._ was investigated using UV/Vis spectrophotometer. It was found that the quaternary phosphonium cation, [PI 4,666]+ is a reasonably stable cation in the presence of 02._ which indicates the possible use of these ILs for further useful applications.

AB - Superoxide ion has been generated in room temperature ionic liquid trihexyl (tetradecyl) phosphonium bis (trifluoromethylsulfonyl)imide, [P14,666][N(Tf)2]. Cyclic voltammetry and chronoamperometry techniques were used for the electrochemical generation of Om2._, while chemical generation was done by adding KO2 to dimethylsulphoxide (DMSO). The long term stability of O2._ was investigated using UV/Vis spectrophotometer. It was found that the quaternary phosphonium cation, [PI 4,666]+ is a reasonably stable cation in the presence of 02._ which indicates the possible use of these ILs for further useful applications.

KW - Ionic liquids

KW - Phosphonium

KW - Stability

KW - Superoxide ion

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Generation of Superoxide Ion in Trihexyl (Tetradecyl) Phosphonium bis (Trifluoromethylsulfonyl) imide Room Temperature Ionic Liquid

Abstract

Keywords

ASJC Scopus subject areas

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