Extractive desulfurization of liquid fuel with FeCl3-based deep eutectic solvents: Experimental design and optimization by central-composite design

Zaharaddeen S. Gano, Farouq S. Mjalli, Talal Al-Wahaibi, Yahya Al-Wahaibi, Inas M. AlNashef

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

The extractive desulfurization of simulated fuel containing dibenzothiophene (DBT) and thiophene as sulfur compounds and commercial diesel was carried out using FeCl3-based deep eutectic solvent (DES). The study was conducted using the response surface method of experimental design technique, which aided in the modeling and optimization of the desulfurization process. High performance liquid chromatography (HPLC) was employed for the quantitative monitoring of the sulfur compounds in the fuel. The results showed that extraction efficiencies as high as 64% and 44% (for DBT and thiophene) could be achieved with the solvent in a single stage extraction, thus showing that the solvent has higher DBT removal than thiophene. Due to their observed extraction performances and zero solubility with the simulated fuel, the solvents were further used for the desulfurization of real commercial diesel and 32% total sulfur removal from the diesel was achieved. The work has not only shown that FeCl3-based DESs can be used in desulfurization of liquid fuels but also proved their desulfurization ability in the presence of multiple component fuel particularly the real commercial diesel fuel whose sulfur content was eventually lowered to below the environmental sulfur regulation in Oman. Finally, it was shown that the DESs were effectively regenerated and reused five times without significant decrease in their sulfur removal ability from both simulated fuel and commercial diesel.

Original languageEnglish
Pages (from-to)10-20
Number of pages11
JournalChemical Engineering and Processing: Process Intensification
Volume93
DOIs
Publication statusPublished - Jul 1 2015

Fingerprint

Liquid fuels
Desulfurization
Design of experiments
Eutectics
Composite materials
Thiophenes
Thiophene
Sulfur Compounds
Sulfur compounds
Sulfur
High performance liquid chromatography
Diesel fuels
Solubility
Monitoring
dibenzothiophene

Keywords

  • Deep eutectic solvents
  • Desulfurization
  • Extraction
  • Ferric chloride
  • Liquid fuels
  • Response surface methodology

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering
  • Energy Engineering and Power Technology
  • Process Chemistry and Technology

Cite this

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title = "Extractive desulfurization of liquid fuel with FeCl3-based deep eutectic solvents: Experimental design and optimization by central-composite design",
abstract = "The extractive desulfurization of simulated fuel containing dibenzothiophene (DBT) and thiophene as sulfur compounds and commercial diesel was carried out using FeCl3-based deep eutectic solvent (DES). The study was conducted using the response surface method of experimental design technique, which aided in the modeling and optimization of the desulfurization process. High performance liquid chromatography (HPLC) was employed for the quantitative monitoring of the sulfur compounds in the fuel. The results showed that extraction efficiencies as high as 64{\%} and 44{\%} (for DBT and thiophene) could be achieved with the solvent in a single stage extraction, thus showing that the solvent has higher DBT removal than thiophene. Due to their observed extraction performances and zero solubility with the simulated fuel, the solvents were further used for the desulfurization of real commercial diesel and 32{\%} total sulfur removal from the diesel was achieved. The work has not only shown that FeCl3-based DESs can be used in desulfurization of liquid fuels but also proved their desulfurization ability in the presence of multiple component fuel particularly the real commercial diesel fuel whose sulfur content was eventually lowered to below the environmental sulfur regulation in Oman. Finally, it was shown that the DESs were effectively regenerated and reused five times without significant decrease in their sulfur removal ability from both simulated fuel and commercial diesel.",
keywords = "Deep eutectic solvents, Desulfurization, Extraction, Ferric chloride, Liquid fuels, Response surface methodology",
author = "Gano, {Zaharaddeen S.} and Mjalli, {Farouq S.} and Talal Al-Wahaibi and Yahya Al-Wahaibi and AlNashef, {Inas M.}",
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T2 - Experimental design and optimization by central-composite design

AU - Gano, Zaharaddeen S.

AU - Mjalli, Farouq S.

AU - Al-Wahaibi, Talal

AU - Al-Wahaibi, Yahya

AU - AlNashef, Inas M.

PY - 2015/7/1

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N2 - The extractive desulfurization of simulated fuel containing dibenzothiophene (DBT) and thiophene as sulfur compounds and commercial diesel was carried out using FeCl3-based deep eutectic solvent (DES). The study was conducted using the response surface method of experimental design technique, which aided in the modeling and optimization of the desulfurization process. High performance liquid chromatography (HPLC) was employed for the quantitative monitoring of the sulfur compounds in the fuel. The results showed that extraction efficiencies as high as 64% and 44% (for DBT and thiophene) could be achieved with the solvent in a single stage extraction, thus showing that the solvent has higher DBT removal than thiophene. Due to their observed extraction performances and zero solubility with the simulated fuel, the solvents were further used for the desulfurization of real commercial diesel and 32% total sulfur removal from the diesel was achieved. The work has not only shown that FeCl3-based DESs can be used in desulfurization of liquid fuels but also proved their desulfurization ability in the presence of multiple component fuel particularly the real commercial diesel fuel whose sulfur content was eventually lowered to below the environmental sulfur regulation in Oman. Finally, it was shown that the DESs were effectively regenerated and reused five times without significant decrease in their sulfur removal ability from both simulated fuel and commercial diesel.

AB - The extractive desulfurization of simulated fuel containing dibenzothiophene (DBT) and thiophene as sulfur compounds and commercial diesel was carried out using FeCl3-based deep eutectic solvent (DES). The study was conducted using the response surface method of experimental design technique, which aided in the modeling and optimization of the desulfurization process. High performance liquid chromatography (HPLC) was employed for the quantitative monitoring of the sulfur compounds in the fuel. The results showed that extraction efficiencies as high as 64% and 44% (for DBT and thiophene) could be achieved with the solvent in a single stage extraction, thus showing that the solvent has higher DBT removal than thiophene. Due to their observed extraction performances and zero solubility with the simulated fuel, the solvents were further used for the desulfurization of real commercial diesel and 32% total sulfur removal from the diesel was achieved. The work has not only shown that FeCl3-based DESs can be used in desulfurization of liquid fuels but also proved their desulfurization ability in the presence of multiple component fuel particularly the real commercial diesel fuel whose sulfur content was eventually lowered to below the environmental sulfur regulation in Oman. Finally, it was shown that the DESs were effectively regenerated and reused five times without significant decrease in their sulfur removal ability from both simulated fuel and commercial diesel.

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