Equation of state of liquid mixtures with non-additive potentials

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6 Citations (Scopus)

Abstract

The equation of state of binary fluids based on a statistical mechanical perturbation scheme is formulated to investigate the impact of the non-additivity of the potential, energy mismatch and size factor of the component species. The hard sphere diameters of the reference system are made temperature dependent. The isothermal and the isobaric curves calculated for segregating, ordered and ideal fluid mixtures are compared with each other.

Original languageEnglish
JournalJournal of Non-Crystalline Solids
Volume250
DOIs
Publication statusPublished - Aug 2 1999

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Equations of state of liquids
equations of state
ideal fluids
binary fluids
Fluids
reference systems
fluids
liquids
Potential energy
Equations of state
potential energy
perturbation
curves
Temperature
temperature

ASJC Scopus subject areas

  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials

Cite this

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title = "Equation of state of liquid mixtures with non-additive potentials",
abstract = "The equation of state of binary fluids based on a statistical mechanical perturbation scheme is formulated to investigate the impact of the non-additivity of the potential, energy mismatch and size factor of the component species. The hard sphere diameters of the reference system are made temperature dependent. The isothermal and the isobaric curves calculated for segregating, ordered and ideal fluid mixtures are compared with each other.",
author = "I. Ali and Osman, {S. M.} and Singh, {R. N.}",
year = "1999",
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language = "English",
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issn = "0022-3093",
publisher = "Elsevier",

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AU - Ali, I.

AU - Osman, S. M.

AU - Singh, R. N.

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N2 - The equation of state of binary fluids based on a statistical mechanical perturbation scheme is formulated to investigate the impact of the non-additivity of the potential, energy mismatch and size factor of the component species. The hard sphere diameters of the reference system are made temperature dependent. The isothermal and the isobaric curves calculated for segregating, ordered and ideal fluid mixtures are compared with each other.

AB - The equation of state of binary fluids based on a statistical mechanical perturbation scheme is formulated to investigate the impact of the non-additivity of the potential, energy mismatch and size factor of the component species. The hard sphere diameters of the reference system are made temperature dependent. The isothermal and the isobaric curves calculated for segregating, ordered and ideal fluid mixtures are compared with each other.

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U2 - 10.1016/S0022-3093(99)00264-1

DO - 10.1016/S0022-3093(99)00264-1

M3 - Article

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JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

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