Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

Christoph Lentsch; Rita Fürst; Uwe Rinner

doi:10.1055/s-0033-1339923

Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

Christoph Lentsch, Rita Fürst, Uwe Rinner^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.

Original language	English
Article number	ST-2013-B0718-L
Pages (from-to)	2665-2670
Number of pages	6
Journal	Synlett
Volume	24
Issue number	20
DOIs	https://doi.org/10.1055/s-0033-1339923
Publication status	Published - Dec 17 2013

Keywords

metathesis
natural products
palladium
stereoselective synthesis
terpenoids

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0033-1339923

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abstract = "A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.",

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AU - Lentsch, Christoph

AU - Fürst, Rita

AU - Rinner, Uwe

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Y1 - 2013/12/17

N2 - A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.

AB - A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.

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KW - natural products

KW - palladium

KW - stereoselective synthesis

KW - terpenoids

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Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

Abstract

Keywords

ASJC Scopus subject areas

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