Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

Christoph Lentsch, Rita Fürst, Uwe Rinner

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.

Original languageEnglish
Article numberST-2013-B0718-L
Pages (from-to)2665-2670
Number of pages6
JournalSynlett
Volume24
Issue number20
DOIs
Publication statusPublished - Dec 17 2013

Fingerprint

Cyclopentanes
Diterpenes
Epoxy Compounds
Palladium
jatrophane

Keywords

  • metathesis
  • natural products
  • palladium
  • stereoselective synthesis
  • terpenoids

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes. / Lentsch, Christoph; Fürst, Rita; Rinner, Uwe.

In: Synlett, Vol. 24, No. 20, ST-2013-B0718-L, 17.12.2013, p. 2665-2670.

Research output: Contribution to journalArticle

Lentsch, Christoph ; Fürst, Rita ; Rinner, Uwe. / Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes. In: Synlett. 2013 ; Vol. 24, No. 20. pp. 2665-2670.
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