Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

Christoph Lentsch; Rita Fürst; Uwe Rinner

doi:10.1055/s-0033-1339923

Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

Christoph Lentsch, Rita Fürst, Uwe Rinner^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.

Original language	English
Article number	ST-2013-B0718-L
Pages (from-to)	2665-2670
Number of pages	6
Journal	Synlett
Volume	24
Issue number	20
DOIs	https://doi.org/10.1055/s-0033-1339923
Publication status	Published - Dec 17 2013
Externally published	Yes

Keywords

metathesis
natural products
palladium
stereoselective synthesis
terpenoids

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/s-0033-1339923

Cite this

@article{c82d006933b844edb8815b507249a057,

title = "Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes",

abstract = "A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.",

keywords = "metathesis, natural products, palladium, stereoselective synthesis, terpenoids",

author = "Christoph Lentsch and Rita F{\"u}rst and Uwe Rinner",

year = "2013",

month = dec,

day = "17",

doi = "10.1055/s-0033-1339923",

language = "English",

volume = "24",

pages = "2665--2670",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "20",

}

TY - JOUR

T1 - Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

AU - Lentsch, Christoph

AU - Fürst, Rita

AU - Rinner, Uwe

PY - 2013/12/17

Y1 - 2013/12/17

N2 - A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.

AB - A short and efficient synthesis of the cyclopentane moiety of the jatrophane diterpene Pl-3 has been developed. The route features an enyne metathesis reaction, and a stereoselective palladium-catalyzed reductive epoxide opening as key steps.

KW - metathesis

KW - natural products

KW - palladium

KW - stereoselective synthesis

KW - terpenoids

UR - http://www.scopus.com/inward/record.url?scp=84886169584&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84886169584&partnerID=8YFLogxK

U2 - 10.1055/s-0033-1339923

DO - 10.1055/s-0033-1339923

M3 - Article

AN - SCOPUS:84886169584

SN - 0936-5214

VL - 24

SP - 2665

EP - 2670

JO - Synlett

JF - Synlett

IS - 20

M1 - ST-2013-B0718-L

ER -

Enyne metathesis approach towards the cyclopentane motif of jatrophane diterpenes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this