Enantiodifferentiation of chiral cationic cages using trapped achiral BF4 - anions as chirotopic probes

Richard Frantz, Christopher S. Grange, Nawal K. Al-Rasbi, Michael D. Ward, Jérôme Lacour

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co4(L)6(BF4)]7+ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

Original languageEnglish
Pages (from-to)1459-1461
Number of pages3
JournalChemical Communications
Issue number14
DOIs
Publication statusPublished - 2007

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Anions
Negative ions
Salts
Ligands
tris(tetrachlorobenzenediolato)phosphate(V)

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Enantiodifferentiation of chiral cationic cages using trapped achiral BF4 - anions as chirotopic probes. / Frantz, Richard; Grange, Christopher S.; Al-Rasbi, Nawal K.; Ward, Michael D.; Lacour, Jérôme.

In: Chemical Communications, No. 14, 2007, p. 1459-1461.

Research output: Contribution to journalArticle

Frantz, Richard ; Grange, Christopher S. ; Al-Rasbi, Nawal K. ; Ward, Michael D. ; Lacour, Jérôme. / Enantiodifferentiation of chiral cationic cages using trapped achiral BF4 - anions as chirotopic probes. In: Chemical Communications. 2007 ; No. 14. pp. 1459-1461.
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