Electronic structure of platinum-containing polyynes

O. Lhost, J. M. Toussaint, J. L. Bredas, H. F. Wittmann, K. Fuhrmann, R. H. Friend, M. S. Khan, J. Lewis

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15 Citations (Scopus)

Abstract

Using an Extended Huckel approach, we investigate the electronic structure of a class of metal-containing polyynes (oligomers and polymers). These systems contain square-planar coordinated platinum sites linked by conjugated sequences of acetylenic units. We mainly focus on the evolution of the first optical transition as a function of the molecule size when going from short oligomers to the polymer. Our primary interest is in establishing the contribution of the metal atoms in the conjugation path.

Original languageEnglish
Pages (from-to)4525-4530
Number of pages6
JournalSynthetic Metals
Volume57
Issue number2 -3 pt 6
Publication statusPublished - Jan 1 1993

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

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    Lhost, O., Toussaint, J. M., Bredas, J. L., Wittmann, H. F., Fuhrmann, K., Friend, R. H., Khan, M. S., & Lewis, J. (1993). Electronic structure of platinum-containing polyynes. Synthetic Metals, 57(2 -3 pt 6), 4525-4530.