Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide

Muhammad Sharif, Ralf Jackstell, Sarim Dastgir, Badria Al-Shihi, Matthias Beller

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

A more efficient telomerization of 1,3-butadiene with carbon dioxide leading to the valuable δ-lactone 1 (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one) is reported. The key to success is the use of a palladium/TOMPP-catalyst system (TOMPP=tris-(o-methoxyphenyl)-phosphine), which provided under optimal conditions significantly increased yields of the desired product and improved catalyst turnover numbers (TON=1500).

Original languageEnglish
Pages (from-to)542-546
Number of pages5
JournalChemCatChem
Volume9
Issue number4
DOIs
Publication statusPublished - Feb 21 2017

Fingerprint

Palladium
butadiene
Butadiene
Carbon Dioxide
carbon dioxide
palladium
Carbon dioxide
Pyrans
catalysts
Catalysts
Lactones
phosphines
products
1,3-butadiene
tris(2-methoxyphenyl)phosphine

Keywords

  • 1,3-butadiene
  • carbon dioxide
  • lactone
  • palladium
  • telomerization

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide. / Sharif, Muhammad; Jackstell, Ralf; Dastgir, Sarim; Al-Shihi, Badria; Beller, Matthias.

In: ChemCatChem, Vol. 9, No. 4, 21.02.2017, p. 542-546.

Research output: Contribution to journalArticle

Sharif, Muhammad ; Jackstell, Ralf ; Dastgir, Sarim ; Al-Shihi, Badria ; Beller, Matthias. / Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide. In: ChemCatChem. 2017 ; Vol. 9, No. 4. pp. 542-546.
@article{f0d77cb0ac544de0a5b6a841f3406f10,
title = "Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide",
abstract = "A more efficient telomerization of 1,3-butadiene with carbon dioxide leading to the valuable δ-lactone 1 (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one) is reported. The key to success is the use of a palladium/TOMPP-catalyst system (TOMPP=tris-(o-methoxyphenyl)-phosphine), which provided under optimal conditions significantly increased yields of the desired product and improved catalyst turnover numbers (TON=1500).",
keywords = "1,3-butadiene, carbon dioxide, lactone, palladium, telomerization",
author = "Muhammad Sharif and Ralf Jackstell and Sarim Dastgir and Badria Al-Shihi and Matthias Beller",
year = "2017",
month = "2",
day = "21",
doi = "10.1002/cctc.201600760",
language = "English",
volume = "9",
pages = "542--546",
journal = "ChemCatChem",
issn = "1867-3880",
publisher = "Wiley - VCH Verlag GmbH & CO. KGaA",
number = "4",

}

TY - JOUR

T1 - Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide

AU - Sharif, Muhammad

AU - Jackstell, Ralf

AU - Dastgir, Sarim

AU - Al-Shihi, Badria

AU - Beller, Matthias

PY - 2017/2/21

Y1 - 2017/2/21

N2 - A more efficient telomerization of 1,3-butadiene with carbon dioxide leading to the valuable δ-lactone 1 (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one) is reported. The key to success is the use of a palladium/TOMPP-catalyst system (TOMPP=tris-(o-methoxyphenyl)-phosphine), which provided under optimal conditions significantly increased yields of the desired product and improved catalyst turnover numbers (TON=1500).

AB - A more efficient telomerization of 1,3-butadiene with carbon dioxide leading to the valuable δ-lactone 1 (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one) is reported. The key to success is the use of a palladium/TOMPP-catalyst system (TOMPP=tris-(o-methoxyphenyl)-phosphine), which provided under optimal conditions significantly increased yields of the desired product and improved catalyst turnover numbers (TON=1500).

KW - 1,3-butadiene

KW - carbon dioxide

KW - lactone

KW - palladium

KW - telomerization

UR - http://www.scopus.com/inward/record.url?scp=85013308950&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85013308950&partnerID=8YFLogxK

U2 - 10.1002/cctc.201600760

DO - 10.1002/cctc.201600760

M3 - Article

VL - 9

SP - 542

EP - 546

JO - ChemCatChem

JF - ChemCatChem

SN - 1867-3880

IS - 4

ER -