Conversion of Oleum papaveris seminis oil into methyl esters via esterification process

Optimization and kinetic study

A. M. Syam, U. Rashid, R. Yunus, H. A. Hamid, S. I. Al-Resayes, I. A. Nehdi, A. H. Al-Muhtaseb

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

This paper presents an acid pre-treatment process and a kinetic study for the esterification reaction of Oleum papaveris seminis oil with methanol in the presence of amberlite 120 as a solid catalyst to convert the oil into methyl esters. Response surface methodology (RSM) was applied to optimize the reaction parameters, i.e. reaction time, percentage of the catalyst and volume ratio of methanol to oil. The results revealed that 0.87% w/w of catalyst concentration and 44.70% v/v of methanol to oil ratio provided final free fatty acid (FFA) contents of 0.60% w/w at 102.40 min of reaction time. It proved that the contribution of Amberlite 120 in the esterification of FFA was highly significant. The kinetics of the esterification in Oleum papaveris seminis oil with methanol in the presence of the amberlite 120 catalyst were also investigated to establish the reaction rate constant (k), reaction order, and activation energy. The study was performed under the optimized parameters at three reaction temperatures (50, 55, and 60 °C). The value of k was in the range of 0.013 to 0.027 min-1. The first-order kinetics' model was suitable for this irreversible FFA esterification with the activation energy of about 60.9 KJ·mol-1.

Original languageEnglish
Article numbere115
JournalGrasas y Aceites
Volume67
Issue number1
DOIs
Publication statusPublished - Jan 1 2016

Fingerprint

Olea
Esterification
esterification
Oils
Esters
catalysts
esters
Methanol
kinetics
methanol
oils
Kinetics
Nonesterified Fatty Acids
free fatty acids
Catalysts
activation energy
Activation energy
response surface methodology
Reaction rates
Rate constants

Keywords

  • Amberlite 120
  • Esterification
  • Kinetics
  • Oleum papaveris seminis oil
  • Response surface methodology

ASJC Scopus subject areas

  • Food Science
  • Organic Chemistry

Cite this

Conversion of Oleum papaveris seminis oil into methyl esters via esterification process : Optimization and kinetic study. / Syam, A. M.; Rashid, U.; Yunus, R.; Hamid, H. A.; Al-Resayes, S. I.; Nehdi, I. A.; Al-Muhtaseb, A. H.

In: Grasas y Aceites, Vol. 67, No. 1, e115, 01.01.2016.

Research output: Contribution to journalArticle

Syam, A. M. ; Rashid, U. ; Yunus, R. ; Hamid, H. A. ; Al-Resayes, S. I. ; Nehdi, I. A. ; Al-Muhtaseb, A. H. / Conversion of Oleum papaveris seminis oil into methyl esters via esterification process : Optimization and kinetic study. In: Grasas y Aceites. 2016 ; Vol. 67, No. 1.
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abstract = "This paper presents an acid pre-treatment process and a kinetic study for the esterification reaction of Oleum papaveris seminis oil with methanol in the presence of amberlite 120 as a solid catalyst to convert the oil into methyl esters. Response surface methodology (RSM) was applied to optimize the reaction parameters, i.e. reaction time, percentage of the catalyst and volume ratio of methanol to oil. The results revealed that 0.87{\%} w/w of catalyst concentration and 44.70{\%} v/v of methanol to oil ratio provided final free fatty acid (FFA) contents of 0.60{\%} w/w at 102.40 min of reaction time. It proved that the contribution of Amberlite 120 in the esterification of FFA was highly significant. The kinetics of the esterification in Oleum papaveris seminis oil with methanol in the presence of the amberlite 120 catalyst were also investigated to establish the reaction rate constant (k), reaction order, and activation energy. The study was performed under the optimized parameters at three reaction temperatures (50, 55, and 60 °C). The value of k was in the range of 0.013 to 0.027 min-1. The first-order kinetics' model was suitable for this irreversible FFA esterification with the activation energy of about 60.9 KJ·mol-1.",
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