Competitive removal of heavy metals from spiked hospital wastewater on acidic and chelating dehydrated carbons

El Said Ibrahim El-Shafey; Saleh Al-Busafi; Haider Al-Lawati; Sheikha Al-Shibli

doi:10.1080/01496395.2016.1212884

Competitive removal of heavy metals from spiked hospital wastewater on acidic and chelating dehydrated carbons

El Said Ibrahim El-Shafey^*, Saleh Al-Busafi, Haider Al-Lawati, Sheikha Al-Shibli

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Date palm leaflets were carbonised using sulphuric acid dehydration, producing acidic dehydrated carbon (DC) that was converted to chelating dehydrated carbon (CDC) using ethylene diamine functionalisation. Both carbons were surface characterised and tested for competitive removal of Cd²⁺, Cu²⁺, Co²⁺, Ni²⁺ and Zn²⁺ from metal mixtures in hospital wastewater (HWW) and deionised water (DW). Sorption kinetics data follow pseudo-second-order model. Equilibrium sorption data follow the Langmuir model with better performance for CDC than DC. Sorption of metals from metal mixture from DW is clearly higher than from HWW because of the high content of organic moieties in HWW.

Original language	English
Pages (from-to)	2348-2359
Number of pages	12
Journal	Separation Science and Technology (Philadelphia)
Volume	51
Issue number	14
DOIs	https://doi.org/10.1080/01496395.2016.1212884
Publication status	Published - Sept 21 2016

Keywords

Carbon
chelating
dehydrated
hospital
metals
sorption

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Process Chemistry and Technology
Filtration and Separation

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10.1080/01496395.2016.1212884

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abstract = "Date palm leaflets were carbonised using sulphuric acid dehydration, producing acidic dehydrated carbon (DC) that was converted to chelating dehydrated carbon (CDC) using ethylene diamine functionalisation. Both carbons were surface characterised and tested for competitive removal of Cd2+, Cu2+, Co2+, Ni2+ and Zn2+ from metal mixtures in hospital wastewater (HWW) and deionised water (DW). Sorption kinetics data follow pseudo-second-order model. Equilibrium sorption data follow the Langmuir model with better performance for CDC than DC. Sorption of metals from metal mixture from DW is clearly higher than from HWW because of the high content of organic moieties in HWW.",

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AU - El-Shafey, El Said Ibrahim

AU - Al-Busafi, Saleh

AU - Al-Lawati, Haider

AU - Al-Shibli, Sheikha

PY - 2016/9/21

Y1 - 2016/9/21

N2 - Date palm leaflets were carbonised using sulphuric acid dehydration, producing acidic dehydrated carbon (DC) that was converted to chelating dehydrated carbon (CDC) using ethylene diamine functionalisation. Both carbons were surface characterised and tested for competitive removal of Cd2+, Cu2+, Co2+, Ni2+ and Zn2+ from metal mixtures in hospital wastewater (HWW) and deionised water (DW). Sorption kinetics data follow pseudo-second-order model. Equilibrium sorption data follow the Langmuir model with better performance for CDC than DC. Sorption of metals from metal mixture from DW is clearly higher than from HWW because of the high content of organic moieties in HWW.

AB - Date palm leaflets were carbonised using sulphuric acid dehydration, producing acidic dehydrated carbon (DC) that was converted to chelating dehydrated carbon (CDC) using ethylene diamine functionalisation. Both carbons were surface characterised and tested for competitive removal of Cd2+, Cu2+, Co2+, Ni2+ and Zn2+ from metal mixtures in hospital wastewater (HWW) and deionised water (DW). Sorption kinetics data follow pseudo-second-order model. Equilibrium sorption data follow the Langmuir model with better performance for CDC than DC. Sorption of metals from metal mixture from DW is clearly higher than from HWW because of the high content of organic moieties in HWW.

KW - Carbon

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KW - sorption

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Competitive removal of heavy metals from spiked hospital wastewater on acidic and chelating dehydrated carbons

Abstract

Keywords

ASJC Scopus subject areas

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