Komparativna simulaciona studija polimerizacije propilena u gasnoj fazi u reaktorima sa fluidizovanim slojem korišćenjem aspen polymers i dvofaznih modela

Translated title of the contribution: Comparative simulation study of gas-phase propylene polymerization in fluidized bed reactors using aspen polymers and two phase models

Ahmad Shamiri, M. A. Hussain, F. S. Mjalli, Navid Mostoufi

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A comparative study describing gas-phase propylene polymerization in fluidized- bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as simulation using the Aspen Polymers process simulator. The two-phase reactor model accounts for the emulsion and bubble phases which contain different portions of catalysts with the polymerization occurring in both phases. Both models predict production rate, molecular weight, polydispersity index (PDI) and melt flow index (MFI) of the polymer. We used both models to investigate the effect of important polymerization parameters, namely catalyst feed rate and hydrogen concentration, on the product polypropylene properties, such as production rate, molecular weight, PDI and MFI. Both the two-phase model and Aspen Polymers simulator showed good agreement in terms of production rate. However, the models differed in their predictions for weight-average molecular weight, PDI and MFI. Based on these results, we propose incorporating the missing hydrodynamic effects into Aspen Polymers to provide a more realistic understanding of the phenomena encountered in fluidized bed reactors for polyolefin production.

Original languageUndefined/Unknown
Pages (from-to)13-24
Number of pages12
JournalChemical Industry and Chemical Engineering Quarterly
Volume19
Issue number1
DOIs
Publication statusPublished - 2013

Fingerprint

Fluidized beds
Propylene
Polymers
Gases
Polymerization
Polydispersity
Molecular weight
Catalysts
Simulators
Polypropylenes
Fluidization
Polyolefins
Emulsions
propylene
Hydrogen
Hydrodynamics

Keywords

  • Aspen polymers
  • Mathematical modeling
  • Polypropylene polymerization
  • Ziegler-Natta catalyst

ASJC Scopus subject areas

  • Chemical Engineering(all)

Cite this

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title = "Komparativna simulaciona studija polimerizacije propilena u gasnoj fazi u reaktorima sa fluidizovanim slojem korišćenjem aspen polymers i dvofaznih modela",
abstract = "A comparative study describing gas-phase propylene polymerization in fluidized- bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as simulation using the Aspen Polymers process simulator. The two-phase reactor model accounts for the emulsion and bubble phases which contain different portions of catalysts with the polymerization occurring in both phases. Both models predict production rate, molecular weight, polydispersity index (PDI) and melt flow index (MFI) of the polymer. We used both models to investigate the effect of important polymerization parameters, namely catalyst feed rate and hydrogen concentration, on the product polypropylene properties, such as production rate, molecular weight, PDI and MFI. Both the two-phase model and Aspen Polymers simulator showed good agreement in terms of production rate. However, the models differed in their predictions for weight-average molecular weight, PDI and MFI. Based on these results, we propose incorporating the missing hydrodynamic effects into Aspen Polymers to provide a more realistic understanding of the phenomena encountered in fluidized bed reactors for polyolefin production.",
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AU - Shamiri, Ahmad

AU - Hussain, M. A.

AU - Mjalli, F. S.

AU - Mostoufi, Navid

PY - 2013

Y1 - 2013

N2 - A comparative study describing gas-phase propylene polymerization in fluidized- bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as simulation using the Aspen Polymers process simulator. The two-phase reactor model accounts for the emulsion and bubble phases which contain different portions of catalysts with the polymerization occurring in both phases. Both models predict production rate, molecular weight, polydispersity index (PDI) and melt flow index (MFI) of the polymer. We used both models to investigate the effect of important polymerization parameters, namely catalyst feed rate and hydrogen concentration, on the product polypropylene properties, such as production rate, molecular weight, PDI and MFI. Both the two-phase model and Aspen Polymers simulator showed good agreement in terms of production rate. However, the models differed in their predictions for weight-average molecular weight, PDI and MFI. Based on these results, we propose incorporating the missing hydrodynamic effects into Aspen Polymers to provide a more realistic understanding of the phenomena encountered in fluidized bed reactors for polyolefin production.

AB - A comparative study describing gas-phase propylene polymerization in fluidized- bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as simulation using the Aspen Polymers process simulator. The two-phase reactor model accounts for the emulsion and bubble phases which contain different portions of catalysts with the polymerization occurring in both phases. Both models predict production rate, molecular weight, polydispersity index (PDI) and melt flow index (MFI) of the polymer. We used both models to investigate the effect of important polymerization parameters, namely catalyst feed rate and hydrogen concentration, on the product polypropylene properties, such as production rate, molecular weight, PDI and MFI. Both the two-phase model and Aspen Polymers simulator showed good agreement in terms of production rate. However, the models differed in their predictions for weight-average molecular weight, PDI and MFI. Based on these results, we propose incorporating the missing hydrodynamic effects into Aspen Polymers to provide a more realistic understanding of the phenomena encountered in fluidized bed reactors for polyolefin production.

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KW - Polypropylene polymerization

KW - Ziegler-Natta catalyst

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