By-products formation in the dehydrogenation of methylcyclohexane

M. R. Usman, D. L. Cresswell, A. A. Garforth

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The selectivity of the by-products' formation for the dehydrogenation of methylcyclohexane (MCH) is studied under varying conditions of temperature, pressure, and feed composition. Benzene, cyclohexane, and ring-closed products (dimethylcyclopentanes and ethylcyclopentane) were found as the major by-products. The yield of these major by-products increased with an increase in the total pressure as well increased hydrogen concentration in the feed. Analyses of benzene and cyclohexane formation reveal cyclohexane is an intermediate in the formation of benzene.

Original languageEnglish
Pages (from-to)2247-2257
Number of pages11
JournalPetroleum Science and Technology
Volume29
Issue number21
DOIs
Publication statusPublished - Jan 2011

Keywords

  • by-products formation
  • disproportionation
  • hydrodemethylation
  • methylcyclohexane dehydrogenation
  • selectivity

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Fuel Technology
  • Geotechnical Engineering and Engineering Geology
  • Energy Engineering and Power Technology

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