A de Vries (SmC*) Phase in a Novel Series of Chiral Fluorinated Organosiloxane Liquid Crystals

Wajdi Zoghaib, Carlo Carboni, Fatma A. Kashoub, Juhaina S. Al-Rushidi, Buthaina Y. Al-Jabri, Aysha S. Al-Alawi, Hayat F. Al-Mendhry

Research output: Contribution to journalArticle

Abstract

The synthesis and characterization of a series of five chiral fluorinated low molar mass (bifurcated tail) organosiloxane materials is presented. The mesogenic moiety is similar to that in the TSiKN65F mesogen reported by Naciri et al., which displays a de Vries-type SmA* phase. The one parameter varied across the series reported herein is the length of the alkyl chain linking the mesogen's core to the bifurcated siloxane tail. One of the five materials displays a de Vries SmC* phase upon cooling from SmA*.

Original languageEnglish
Pages (from-to)54-64
Number of pages11
JournalMolecular Crystals and Liquid Crystals
Volume666
Issue number1
DOIs
Publication statusPublished - May 3 2018

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Liquid Crystals
siloxanes
Liquid crystals
liquid crystals
Siloxanes
cooling
Molar mass
synthesis
Cooling

Keywords

  • bifurcated siloxane tail
  • chiral
  • de-Vries phase
  • smectic

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

A de Vries (SmC*) Phase in a Novel Series of Chiral Fluorinated Organosiloxane Liquid Crystals. / Zoghaib, Wajdi; Carboni, Carlo; Kashoub, Fatma A.; Al-Rushidi, Juhaina S.; Al-Jabri, Buthaina Y.; Al-Alawi, Aysha S.; Al-Mendhry, Hayat F.

In: Molecular Crystals and Liquid Crystals, Vol. 666, No. 1, 03.05.2018, p. 54-64.

Research output: Contribution to journalArticle

Zoghaib, Wajdi ; Carboni, Carlo ; Kashoub, Fatma A. ; Al-Rushidi, Juhaina S. ; Al-Jabri, Buthaina Y. ; Al-Alawi, Aysha S. ; Al-Mendhry, Hayat F. / A de Vries (SmC*) Phase in a Novel Series of Chiral Fluorinated Organosiloxane Liquid Crystals. In: Molecular Crystals and Liquid Crystals. 2018 ; Vol. 666, No. 1. pp. 54-64.
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AU - Al-Jabri, Buthaina Y.

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