A compact, trinuclear, circular helicate with oxine-based N,O-chelating binding domains

Muna R.A. Al-Mandhary, Peter J. Steel

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The preparation of a silver triflate complex (5) of 1,3-bis(8-quinolyloxymethyl)benzene (4) is described. An x-ray crystal structure determination reveals that it is a compact circular helicate in which three silver atoms are bridged by three ligands in a cyclic array, with additional stabilisation via intramolecular π-π stacking interactions.

Original languageEnglish
Pages (from-to)954-957
Number of pages4
JournalInorganic Chemistry Communications
Volume5
Issue number11
DOIs
Publication statusPublished - Nov 1 2002

Fingerprint

Oxyquinoline
Chelation
Benzene
Silver
Stabilization
Crystal structure
silver
Ligands
X rays
Atoms
stabilization
benzene
preparation
ligands
crystal structure
atoms
x rays
interactions
trifluoromethanesulfonic acid

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

A compact, trinuclear, circular helicate with oxine-based N,O-chelating binding domains. / Al-Mandhary, Muna R.A.; Steel, Peter J.

In: Inorganic Chemistry Communications, Vol. 5, No. 11, 01.11.2002, p. 954-957.

Research output: Contribution to journalArticle

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