Abstract
The title compound, 5,5′-bis(trimethylsilylethynyl)-2,2′- bipyridine, C20H24N2Si2, is a trimethylsilyl-protected dialkyne. It is a precursor in the preparation of platinum di-yne complexes and platinum poly-yne polymers. Such organic compounds are of interest because of the extended π-conjugation that occurs through the hetero-aromatic linker unit in the molecular backbone. Within the molecule, the silylalkyne groups are essentially linear and the bipyridine unit is approximately planar with a dihedral angle of 5.3 (1)° between the planes.
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 60 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - May 2004 |
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ASJC Scopus subject areas
- Structural Biology
- Condensed Matter Physics
Cite this
5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine. / Khan, Muhammad S.; Ahrens, Birte; Male, Louise; Raithby, Paul R.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 5, 05.2004.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - 5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine
AU - Khan, Muhammad S.
AU - Ahrens, Birte
AU - Male, Louise
AU - Raithby, Paul R.
PY - 2004/5
Y1 - 2004/5
N2 - The title compound, 5,5′-bis(trimethylsilylethynyl)-2,2′- bipyridine, C20H24N2Si2, is a trimethylsilyl-protected dialkyne. It is a precursor in the preparation of platinum di-yne complexes and platinum poly-yne polymers. Such organic compounds are of interest because of the extended π-conjugation that occurs through the hetero-aromatic linker unit in the molecular backbone. Within the molecule, the silylalkyne groups are essentially linear and the bipyridine unit is approximately planar with a dihedral angle of 5.3 (1)° between the planes.
AB - The title compound, 5,5′-bis(trimethylsilylethynyl)-2,2′- bipyridine, C20H24N2Si2, is a trimethylsilyl-protected dialkyne. It is a precursor in the preparation of platinum di-yne complexes and platinum poly-yne polymers. Such organic compounds are of interest because of the extended π-conjugation that occurs through the hetero-aromatic linker unit in the molecular backbone. Within the molecule, the silylalkyne groups are essentially linear and the bipyridine unit is approximately planar with a dihedral angle of 5.3 (1)° between the planes.
UR - http://www.scopus.com/inward/record.url?scp=18444365282&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=18444365282&partnerID=8YFLogxK
U2 - 10.1107/S1600536804010128
DO - 10.1107/S1600536804010128
M3 - Article
AN - SCOPUS:18444365282
VL - 60
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 5
ER -