Upcycling brewer's spent grain waste into activated carbon and carbon nanotubes for energy and other applications via two-stage activation

Ahmed I. Osman*, Edward O'Connor, Glenn McSpadden, Jehad K. Abu-Dahrieh, Charlie Farrell, Ala'a H. Al-Muhtaseb, John Harrison, David W. Rooney

*المؤلف المقابل لهذا العمل

نتاج البحث: المساهمة في مجلةمراجعة النظراء

46 اقتباسات (Scopus)

ملخص

BACKGROUND: Brewer's Spent Grain (BSG), a form of lignocellulosic biomass more commonly known as barley waste was used to synthesize activated carbon (AC) and carbon nanotubes (CNTs). The produced materials were used in water remediation application. RESULTS: A novel approach involving two activation steps; first, with phosphoric acid (designated BAC-P) and then using potassium hydroxide (designated BAC-K) was proposed for the production of AC and CNTs from BSG. The AC produced showed a surface area as high as 692.3 m2 g−1 with a pore volume of 0.44 cm3 g−1. This can help aid and facilitate the circular economy by effectively upcycling and valorizing waste lignocellulosic biomass to high surface area AC and subsequently, multi-walled carbon nanotubes (MWCNTs). Consequently, MWCNTs were prepared from the produced AC by mixing it with the nitrogen (N)-based material melamine and iron precursor, iron (III) oxalate hexahydrate, where it produced hydrophilic MWCNTs. Both AC and CNT materials were used in heavy metal removal (HMR), where the maximum lead absorption was observed for sample BAC-K with 77% removal capacity after the first hour of testing. CONCLUSION: This result signifies that the synthesis of these upcycled materials can have an application in the areas of wastewater treatment or other AC/CNT end uses with a rapid cycle time.

اللغة الأصليةEnglish
الصفحات (من إلى)183-195
عدد الصفحات13
دوريةJournal of Chemical Technology and Biotechnology
مستوى الصوت95
رقم الإصدار1
المعرِّفات الرقمية للأشياء
حالة النشرPublished - يناير 1 2020

ASJC Scopus subject areas

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بصمة

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