ملخص
Title full: Synthesis of bridged and linked ruthenium and osmium carbonyl clusters containing a [Au2(Ph2PCH2CH2PPh2 )]2+ unit. The crystal and molecular structures of Ru5C(CO)14Au2(Ph2PCH2 CH2PPh2) and {Os4H3(CO)12}2Au2 (Ph2PCH2CH2PPh2). Treatment of Au2(Ph2PCH2CH2PPh2 )Cl2 with one equivalent of the [Ru5C(CO)14]2- dianion in the presence of TlPF6 gives Ru5C(CO)14Au2(Ph2PCH2 CH2PPh2) (1) in good yield and the [{Ru5C(CO)14}2Au2(Ph 2PCH2CH2PPh2)]2- (2) anion in low yield. Complex 2 becomes the major product if 2 equivalents of [Ru5C(CO)14]2- are used. Reaction of [Au2(Ph2PCH2CH2PPh2 )Cl2] with 3 equivalents of [H3Os4(CO)12]- anion in the presence of TlPF6 affords {H3Os4(CO)12}2Au2 (Ph2PCH2CH2PPh2) (3) in reasonable yield. X-ray diffraction studies of 1 and 3 show that they contain the [Au2(Ph2PCH2CH2PPh 2)]2+ fragment in different coordination modes.
اللغة الأصلية | English |
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الصفحات (من إلى) | C11-C13 |
دورية | Journal of Organometallic Chemistry |
مستوى الصوت | 443 |
رقم الإصدار | 1 |
المعرِّفات الرقمية للأشياء | |
حالة النشر | Published - يناير 12 1993 |
منشور خارجيًا | نعم |
ASJC Scopus subject areas
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- ???subjectarea.asjc.1600.1606???
- ???subjectarea.asjc.1600.1605???
- ???subjectarea.asjc.1600.1604???
- ???subjectarea.asjc.2500.2505???