Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)2Ru(Cl)(C≡C-C6H4-p-NO 2)], [(dppe)2Ru(Cl)(C≡C-C6H3-o-CH 3-p-NO2)]

Muhammad Younus; Nicholas J. Long; Paul R. Raithby; Jack Lewis; Nicola A. Page; Andrew J.P. White; David J. Williams; Michael C.B. Colbert; Andrew J. Hodge; Muhammad S. Khan; David G. Parker

doi:10.1016/S0022-328X(98)01123-1

Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)₂Ru(Cl)(C≡C-C₆H₄-p-NO ₂)], [(dppe)₂Ru(Cl)(C≡C-C₆H₃-o-CH ₃-p-NO₂)]

Muhammad Younus, Nicholas J. Long^*, Paul R. Raithby, Jack Lewis, Nicola A. Page, Andrew J.P. White, David J. Williams, Michael C.B. Colbert, Andrew J. Hodge, Muhammad S. Khan, David G. Parker

^*المؤلف المقابل لهذا العمل

Chemistry

نتاج البحث: المساهمة في مجلة › Article › مراجعة النظراء

58 اقتباسات (Scopus)

ملخص

The synthesis of a series of metal mono-acetylides trans-[(dppe)₂Ru(Cl)(C≡C-R)] (R = C₆H₄-p-C₆H₅, C₆H₄-p-CH₃, C₆H₄-p-NO₂, C₆H₃-o-CH₃-p-NO₂, dppe = Ph₂PCH₂CH₂PPh₂), and unsymmetrical metal bis-acetylides trans-[(dppm)₂M(C≡C-R)(C≡C-R′)]; (M = Ru, Os; R = C₆H₄-p-NO₂, R′ = C₆H₅, C₆H₄-p-CH₃; R = C₆H₅, R′ = C₆H₄-p-C₆H₃) using a variety of σ-acetylide coupling reactions is reported. Three compounds have been structurally characterised, including the unsymmetrical trans-[(dppm)₂Os(C≡C-R)(C≡C-R′)] (R = C₆H₄-p-CH₃, R′ = C₆H₄-p-NO₂] which shows the 'rigid-rod' nature of the acetylide-metal-acetylide linkage. The electrochemistry of symmetrical and unsymmetrical Ru(II) complexes demonstrates the role of the acetylide and the auxiliary ligands in determining the ease of oxidation at the metal centre whilst UV-vis spectral changes illustrate the influence of electron-withdrawing and -donating ligands.

اللغة الأصلية	English
الصفحات (من إلى)	198-209
عدد الصفحات	12
دورية	Journal of Organometallic Chemistry
مستوى الصوت	578
رقم الإصدار	1-2
المعرِّفات الرقمية للأشياء	https://doi.org/10.1016/S0022-328X(98)01123-1
حالة النشر	Published - أبريل 22 1999

ASJC Scopus subject areas

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الوصول إلى المستند

10.1016/S0022-328X(98)01123-1

الملفات والروابط الأخرى

بصمة

أدرس بدقة موضوعات البحث “Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)₂Ru(Cl)(C≡C-C₆H₄-p-NO ₂)], [(dppe)₂Ru(Cl)(C≡C-C₆H₃-o-CH ₃-p-NO₂)]'. فهما يشكلان معًا بصمة فريدة.

قم بذكر هذا

Younus, M., Long, N. J., Raithby, P. R., Lewis, J., Page, N. A., White, A. J. P., Williams, D. J., Colbert, M. C. B., Hodge, A. J., Khan, M. S., & Parker, D. G. (1999). Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)₂Ru(Cl)(C≡C-C₆H₄-p-NO ₂)], [(dppe)₂Ru(Cl)(C≡C-C₆H₃-o-CH ₃-p-NO₂)]. Journal of Organometallic Chemistry, 578(1-2), 198-209. https://doi.org/10.1016/S0022-328X(98)01123-1

Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)₂Ru(Cl)(C≡C-C₆H₄-p-NO ₂)], [(dppe)₂Ru(Cl)(C≡C-C₆H₃-o-CH ₃-p-NO₂)]. / Younus, Muhammad; Long, Nicholas J.; Raithby, Paul R. وآخرون.
في: Journal of Organometallic Chemistry, المجلد 578, رقم 1-2, ٢٢.٠٤.١٩٩٩, صفحة 198-209.

نتاج البحث: المساهمة في مجلة › Article › مراجعة النظراء

Younus, M, Long, NJ, Raithby, PR, Lewis, J, Page, NA, White, AJP, Williams, DJ, Colbert, MCB, Hodge, AJ, Khan, MS & Parker, DG 1999, 'Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)₂Ru(Cl)(C≡C-C₆H₄-p-NO ₂)], [(dppe)₂Ru(Cl)(C≡C-C₆H₃-o-CH ₃-p-NO₂)]', Journal of Organometallic Chemistry, المجلد 578, رقم 1-2, الصفحات 198-209. https://doi.org/10.1016/S0022-328X(98)01123-1

Younus M, Long NJ, Raithby PR, Lewis J, Page NA, White AJP وآخرون. Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)₂Ru(Cl)(C≡C-C₆H₄-p-NO ₂)], [(dppe)₂Ru(Cl)(C≡C-C₆H₃-o-CH ₃-p-NO₂)]. Journal of Organometallic Chemistry. 1999 أبريل 22;578(1-2):198-209. doi: 10.1016/S0022-328X(98)01123-1

Younus, Muhammad ; Long, Nicholas J. ; Raithby, Paul R. وآخرون. / Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium : X-ray structure determinations on [(dppe)₂Ru(Cl)(C≡C-C₆H₄-p-NO ₂)], [(dppe)₂Ru(Cl)(C≡C-C₆H₃-o-CH ₃-p-NO₂)]. في: Journal of Organometallic Chemistry. 1999 ; المجلد 578, رقم 1-2. الصفحات 198-209.

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title = "Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)2Ru(Cl)(C≡C-C6H4-p-NO 2)], [(dppe)2Ru(Cl)(C≡C-C6H3-o-CH 3-p-NO2)]",

abstract = "The synthesis of a series of metal mono-acetylides trans-[(dppe)2Ru(Cl)(C≡C-R)] (R = C6H4-p-C6H5, C6H4-p-CH3, C6H4-p-NO2, C6H3-o-CH3-p-NO2, dppe = Ph2PCH2CH2PPh2), and unsymmetrical metal bis-acetylides trans-[(dppm)2M(C≡C-R)(C≡C-R′)]; (M = Ru, Os; R = C6H4-p-NO2, R′ = C6H5, C6H4-p-CH3; R = C6H5, R′ = C6H4-p-C6H3) using a variety of σ-acetylide coupling reactions is reported. Three compounds have been structurally characterised, including the unsymmetrical trans-[(dppm)2Os(C≡C-R)(C≡C-R′)] (R = C6H4-p-CH3, R′ = C6H4-p-NO2] which shows the 'rigid-rod' nature of the acetylide-metal-acetylide linkage. The electrochemistry of symmetrical and unsymmetrical Ru(II) complexes demonstrates the role of the acetylide and the auxiliary ligands in determining the ease of oxidation at the metal centre whilst UV-vis spectral changes illustrate the influence of electron-withdrawing and -donating ligands.",

keywords = "Acetylide, Electrochemistry, Osmium, Ruthenium",

author = "Muhammad Younus and Long, {Nicholas J.} and Raithby, {Paul R.} and Jack Lewis and Page, {Nicola A.} and White, {Andrew J.P.} and Williams, {David J.} and Colbert, {Michael C.B.} and Hodge, {Andrew J.} and Khan, {Muhammad S.} and Parker, {David G.}",

note = "Funding Information: The authors thank the Cambridge Commonwealth Trust for a Scholarship and Shahjalal University of Science and Technology, Bangladesh, for study leave (MY), the British Council (MCBC), ICI, Wilton (AH and NP) for financial assistance and Johnson Matthey PLC ({\textquoteleft}JM{\textquoteright}) for the loan of precious metals.",

year = "1999",

month = apr,

day = "22",

doi = "10.1016/S0022-328X(98)01123-1",

language = "English",

volume = "578",

pages = "198--209",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

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TY - JOUR

T1 - Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium

T2 - X-ray structure determinations on [(dppe)2Ru(Cl)(C≡C-C6H4-p-NO 2)], [(dppe)2Ru(Cl)(C≡C-C6H3-o-CH 3-p-NO2)]

AU - Younus, Muhammad

AU - Long, Nicholas J.

AU - Raithby, Paul R.

AU - Lewis, Jack

AU - Page, Nicola A.

AU - White, Andrew J.P.

AU - Williams, David J.

AU - Colbert, Michael C.B.

AU - Hodge, Andrew J.

AU - Khan, Muhammad S.

AU - Parker, David G.

N1 - Funding Information: The authors thank the Cambridge Commonwealth Trust for a Scholarship and Shahjalal University of Science and Technology, Bangladesh, for study leave (MY), the British Council (MCBC), ICI, Wilton (AH and NP) for financial assistance and Johnson Matthey PLC (‘JM’) for the loan of precious metals.

PY - 1999/4/22

Y1 - 1999/4/22

N2 - The synthesis of a series of metal mono-acetylides trans-[(dppe)2Ru(Cl)(C≡C-R)] (R = C6H4-p-C6H5, C6H4-p-CH3, C6H4-p-NO2, C6H3-o-CH3-p-NO2, dppe = Ph2PCH2CH2PPh2), and unsymmetrical metal bis-acetylides trans-[(dppm)2M(C≡C-R)(C≡C-R′)]; (M = Ru, Os; R = C6H4-p-NO2, R′ = C6H5, C6H4-p-CH3; R = C6H5, R′ = C6H4-p-C6H3) using a variety of σ-acetylide coupling reactions is reported. Three compounds have been structurally characterised, including the unsymmetrical trans-[(dppm)2Os(C≡C-R)(C≡C-R′)] (R = C6H4-p-CH3, R′ = C6H4-p-NO2] which shows the 'rigid-rod' nature of the acetylide-metal-acetylide linkage. The electrochemistry of symmetrical and unsymmetrical Ru(II) complexes demonstrates the role of the acetylide and the auxiliary ligands in determining the ease of oxidation at the metal centre whilst UV-vis spectral changes illustrate the influence of electron-withdrawing and -donating ligands.

AB - The synthesis of a series of metal mono-acetylides trans-[(dppe)2Ru(Cl)(C≡C-R)] (R = C6H4-p-C6H5, C6H4-p-CH3, C6H4-p-NO2, C6H3-o-CH3-p-NO2, dppe = Ph2PCH2CH2PPh2), and unsymmetrical metal bis-acetylides trans-[(dppm)2M(C≡C-R)(C≡C-R′)]; (M = Ru, Os; R = C6H4-p-NO2, R′ = C6H5, C6H4-p-CH3; R = C6H5, R′ = C6H4-p-C6H3) using a variety of σ-acetylide coupling reactions is reported. Three compounds have been structurally characterised, including the unsymmetrical trans-[(dppm)2Os(C≡C-R)(C≡C-R′)] (R = C6H4-p-CH3, R′ = C6H4-p-NO2] which shows the 'rigid-rod' nature of the acetylide-metal-acetylide linkage. The electrochemistry of symmetrical and unsymmetrical Ru(II) complexes demonstrates the role of the acetylide and the auxiliary ligands in determining the ease of oxidation at the metal centre whilst UV-vis spectral changes illustrate the influence of electron-withdrawing and -donating ligands.

KW - Acetylide

KW - Electrochemistry

KW - Osmium

KW - Ruthenium

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U2 - 10.1016/S0022-328X(98)01123-1

DO - 10.1016/S0022-328X(98)01123-1

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AN - SCOPUS:0000974860

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