ملخص
The synthesis of vinylidene, trans-[(dppm)2ClMCC(H)(R)]PF6, and σ-acetylide complexes, trans-[(dppm)2ClMCCR] (M = Ru, Os; dppm = bis(diphenylphosphino)methane, Ph2PCH2PPh2; R = p-C6H5, p-C6H4C6H5, p-C6H42, C6H32-(CH3)-4-NO2, p-C6H4CH3), and a single-crystal X-ray determination of trans-[(dppm)2ClRuCCC6H4-p-NO2] are reported. The metal-phosphine fragment in these complexes acts as a donor and communicates with the para-substituted nitro acceptor group through the backbone. Such an interaction helps create a delocalized charge-transfer state from the donor to the acceptor.
اللغة الأصلية | English |
---|---|
الصفحات (من إلى) | 205-210 |
عدد الصفحات | 6 |
دورية | Journal of Organometallic Chemistry |
مستوى الصوت | 488 |
رقم الإصدار | 1-2 |
المعرِّفات الرقمية للأشياء | |
حالة النشر | Published - فبراير 22 1995 |
منشور خارجيًا | نعم |
ASJC Scopus subject areas
- ???subjectarea.asjc.1300.1303???
- ???subjectarea.asjc.1600.1606???
- ???subjectarea.asjc.1600.1605???
- ???subjectarea.asjc.1600.1604???
- ???subjectarea.asjc.2500.2505???