Applications of pulsed field gradient spin-echo measurements to the determination of molecular diffusion (and thus size) in organometallic chemistry

نتاج البحث: المساهمة في مجلةمراجعة النظراء

107 اقتباسات (Scopus)

ملخص

Pulsed field gradient spin-echo (PGSE) measurements on (a) four arsine complexes of Pd(II), PdCl2L2 (L = AsMexPh3-x (x = 3-0)), (b) three different ferrocene phosphine dendrimers, and (c) a selection of other organometallic complexes of differing molecular weight, are demonstrated to provide a practical alternative to classical methods used in organometallic chemistry for estimating molecular size. PGSE measurements make use of translational and not rotational properties of molecules and will be especially valuable where one cannot isolate an unknown complex and/or where a side product is of especial interest, since one can measure several components of the mixture simultaneously.

اللغة الأصليةEnglish
الصفحات (من إلى)2551-2555
عدد الصفحات5
دوريةOrganometallics
مستوى الصوت19
رقم الإصدار13
المعرِّفات الرقمية للأشياء
حالة النشرPublished - 2000
منشور خارجيًانعم

ASJC Scopus subject areas

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