TY - JOUR
T1 - A model equation of state of liquid C60 and thermodynamic properties along the liquid-vapour coexistence curve
AU - Khedr, M. Bahaa
AU - Al-Busaidy, M. S.
AU - Osman, S. M.
PY - 2005/7/20
Y1 - 2005/7/20
N2 - We present a model equation of state for C60 based on a variational series mean spherical approximation for a double Yukawa fluid. This allows us to investigate the liquid-vapour coexistence curve and calculate the thermodynamic properties of liquid C60. The comparisons with computer simulation results, based on the Girifalco potential, suggest the importance of treating the attractive tail of the potential accurately. The estimated critical parameters, Tc = 1943 K, ρc = 0.477 nm -3 and Pc = 34.2 bar, are in good agreement with Gibbs ensemble Monte Carlo simulation predictions. The results are discussed, making reference to previous studies.
AB - We present a model equation of state for C60 based on a variational series mean spherical approximation for a double Yukawa fluid. This allows us to investigate the liquid-vapour coexistence curve and calculate the thermodynamic properties of liquid C60. The comparisons with computer simulation results, based on the Girifalco potential, suggest the importance of treating the attractive tail of the potential accurately. The estimated critical parameters, Tc = 1943 K, ρc = 0.477 nm -3 and Pc = 34.2 bar, are in good agreement with Gibbs ensemble Monte Carlo simulation predictions. The results are discussed, making reference to previous studies.
UR - http://www.scopus.com/inward/record.url?scp=22144462870&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=22144462870&partnerID=8YFLogxK
U2 - 10.1088/0953-8984/17/28/002
DO - 10.1088/0953-8984/17/28/002
M3 - Article
AN - SCOPUS:22144462870
SN - 0953-8984
VL - 17
SP - 4411
EP - 4422
JO - Journal of Physics Condensed Matter
JF - Journal of Physics Condensed Matter
IS - 28
ER -